NSRRC Activity Report 2023

168 NSRRC ACTIVITY REPORT 2023 ( 胡志偉 ), San-Yuan Chen*( 陳三元 ), and Yan-Gu Lin*( 林彥谷 ), “ Zhang-rice Singlets State Formed by Two-step Oxidation for Triggering Water Oxidation Under Operando Conditions ”, Nat. Commun. 14 , 529 (2023). • Praveen Kumar Saravanan, Dinesh Bhalothia*, Guo-Heng Huang, Amisha Beniwal, Mingxing Cheng, Yu-Chieh Chao, Ming-Wei Lin, Po-Chun Chen* ( 陳柏鈞 ), and Tsan-Yao Chen*( 陳燦耀 ), “ Sub-Millisecond Laser-irradiation- mediated Surface Restructure Boosts the CO Production Yield of Cobalt Oxide Supported Pd Nanoparticles ”, Nanomaterials 13 , 1801 (2023). • Walter Sebastian Scheld*, Kwangnam Kim, Christian Schwab, Alexandra C. Moy, Shi-Kai Jiang, Markus Mann, Christian Dellen, Yoo Jung Sohn, Sandra Lobe, Martin Ihrig, Michael Gregory Danner, Chia-Yu Chang, Sven Uhlenbruck, Eric D. Wachsman, Bing Joe Hwang, Jeff Sakamoto, Liwen F. Wan, Brandon C. Wood, Martin Finsterbusch, and Dina Fattakhova-Rohlfing*, “ The Riddle of Dark LLZO: Cobalt Diffusion in Garnet Separators of Solid-state Lithium Batteries ”, Adv. Funct. Mater. 33 , 2302939 (2023). ◎ Bereket Woldegbreal Taklu, Yosef Nikodimos, Hailemariam Kassa Bezabh, Keseven Lakshmanan, Teklay Mezgebe Hagos, Teshome Assefa Nigatu, Semaw Kebede Merso, Hung-Yi Sung, Sheng-Chiang Yang, She-Huang Wu, Wei-Nien Su*( 蘇威年 ), Bing Joe Hwang*( 黃炳照 ), “ Air-stable Iodized-oxychloride Argyrodite Sulfide and Anionic Swap on the Practical Potential Window for All- solid-state Lithium-metal Batteries ”, Nano Energy 112 , 108471 (2023). • Angelina Melanita Tarigan, Sofiannisa Aulia, Mia Rinawati, Ling-Yu Chang* ( 張玲毓 ), Yao-Sheng Cheng, Ching-Cheng Chang, Wei-Hsiang Huang* ( 黃偉翔 ), Jeng-Lung Chen, Heru Setyawan, and Min-Hsin Yeh*( 葉旻鑫 ), “ Tandem Surface Engineering of Graphene Quantum Dot-assisted Fluorinated NiFe Prussian Blue Analogue for Electrocatalytic Oxygen Evolution Reaction ”, Chem. Eng. J. 476 , 146754 (2023). ◎ Nigusu Tiruneh Temesgen, Hailemariam Kassa Bezabh, Misganaw Adigo Weret, Kassie Nigus Shitaw, Yosef Nikodimos, Bereket Woldegbreal Taklu, Keseven Lakshmanan, Sheng-Chiang Yang, Shi-Kai Jiang, Chen-Jui Huang, She-Huang Wu*( 吳溪煌 ), Wei-Nien Su*( 蘇威年 ), Bing Joe Hwang*( 黃炳照 ), “ Solvent-free Design of Argyrodite Sulfide Composite Solid Electrolyte with Superb Interface and Moisture Stability in Anode-free Lithium Metal Batteries ”, J. Power Sources 556 , 232462 (2023). • Dien-Thien To, Joon Ching Juan, Meng-Hsuan Tsai, Chia-Hsin Wang, Chih- Wen Pao, Chi-Liang Chen*( 陳啟亮 ), Yu-Chuan Lin*( 林裕川 ), “ Conversion of CO 2 to Light Hydrocarbons by Using FeC x Catalysts Derived from Iron Nitrate Co-pyrolyzing with Melamine, Bulk g-C 3 N 4 , or Defective g-C 3 N 4 ”, Catal. Surv. Asia 27 , 260 (2023). • Kuangye Wang, Ling Lee, Sueh Liang Loo, Tzu-Yi Yang, Chieh-Ting Chen, Tzu- Wen Kuo, Jeng-Lung Chen, Hao-chung Kuo, and Yu-Lun Chueh*( 闕郁倫 ), “ Controllable Vertical Nitrogen Doping in Nanoscaled Molybdenum Diselenide Films for Selective Sensing of NH 3 and NO 2 Gases ”, ACS Appl. Nano Mater. 6 , 5336 (2023). • Chueh-Cheng Yang, Meng-Hsuan Tsai, Zong-Ren Yang, Yaw-Wen Yang* ( 楊耀文 ), Yuan-Chieh Tseng*( 曾院介 ), and Chia-Hsin Wang*( 王嘉興 ), “ An Effective Charge Neutralization Enabled by Graphene Overlayer in Ambient Pressure XPS Measurements of Insulators ”, Adv. Mater. Interfaces 10 , 2201926 (2023). ◎ Chueh-Cheng Yang, Meng-Hsuan Tsai, Zong-Ren Yang, Yuan-Chieh Tseng* ( 曾院介 ), and Chia-Hsin Wang*( 王嘉興 ), “ Revealing the Surface Species Evolution on Low-loading Platinum in an Electrochemical Redox Reaction by Operando Ambient-pressure X-ray Phtoelectron Spectroscopy ”, ChemCatChem 15 , e202300359 (2023). • Thomas Yang, Dinesh Bhalothia, Hong-Wei Chang, Che Yan, Amisha Beniwal, You-Xun Chang, Shun-Chi Wu, Po-Chun Chen, Kuan-Wen Wang*( 王冠文 ), Sheng Dai*( 戴升 ), Tsan-Yao Chen*( 陳燦耀 ), “ Oxygen Vacancies Endow Atomic Cobalt-palladium Oxide Clusters with Outstanding Oxygen Reduction Reaction Activity ”, Chem. Eng. J. 454 , 140289 (2023). TLS SP12B1 BM − Materials X-ray Study • Dinesh Bhalothia, Che Yan, Nozomu Hiraoka, Hirofumi Ishii, Yen-Fa Liao, Po-Chun Chen, Kuan-Wen Wang, Jyh-Pin Chou, Sheng Dai*( 戴升 ), and Tsan- Yao Chen*( 陳燦耀 ), “ Pt-Mediated Interface Engineering Boosts the Oxygen Reduction Reaction Performance of Ni Hydroxide-supported Pd Nanoparticles ”, ACS Appl. Mater. Interfaces 15 , 16177 (2023). • Tong Han, Xing Cao*( 曹興 ), Hsiao-Chien Chen, Junguo Ma, Yuan Yu, Yuhuan Li, Wei Xu, Kaian Sun, Aijian Huang, Zheng Chen, Chen Chen, Hongjun Zhang, Bangjiao Ye, Qing Peng*( 彭卿 ), and Yadong Li*( 李亞 棟 ), “ Photosynthesis of Benzonitriles on BiOBr Nanosheets Promoted by Vacancy Associates ”, Angew. Chem. Int. Edit. 62 , e202313325 (2023). • Yanan Hao, Feng Hu*( 胡峰 ), Shangqian Zhu, Yajie Sun, Hui Wang, Luqi Wang, Ying Wang, Jianjun Xue, Yen-Fa Liao, Minhua Shao, and Shengjie Peng*( 彭生杰 ), “ MXene-regulated Metal-oxide Interfaces with Modified Intermediate Configurations Realizing Nearly 100% CO 2 Electrocatalytic Conversion ”, Angew. Chem. Int. Edit. 62 , e202304179 (2023). • Kazumasa Horigane*, Masayuki Tadokoro, Ritsuko Eguchi, Hirofumi Ishii, Shinichi Nakamura, Takashi Kambe, Naoshi Ikeda, Hidenori Goto, Yoshihiro Kubozono, and Jun Akimitsu, “ Structural Characterization of Graphite Analogue BC x Synthesized Under Various Conditions and Its Application to Ti Intercalation ”, Inorg. Chem. 62 , 19466 (2023). ◎ Chia-Shuo Hsu, Jiali Wang, You-Chiuan Chu, Jui-Hsien Chen, Chia-Ying Chien, Kuo-Hsin Lin, Li Duan Tsai, Hsiao-Chien Chen, Yen-Fa Liao, Nozomu Hiraoka, Yuan-Chung Cheng*( 鄭原忠 ), and Hao Ming Chen*( 陳浩銘 ), “ Activating Dynamic Atomic-configuration for Single-site Electrocatalyst in Electrochemical CO 2 Reduction ”, Nat. Commun. 14 , 5245 (2023). • Weibo Hua*( 滑緯博 ), Jilu Zhang, Suning Wang, Yi Cheng, Hang Li, Jochi Tseng, Zhonghua Wu, Chong-Heng Shen, Oleksandr Dolotko, Hao Liu, Sung-Fu Hung, Wei Tang*( 唐偉 ), Mingtao Li, Michael Knapp, Helmut Ehrenberg, Sylvio Indris*, and Xiaodong Guo*( 郭孝東 ), “ Long-range Cationic Disordering Induces two Distinct Degradation Pathways in Co-free Ni-rich Layered Cathodes ”, Angew. Chem. Int. Edit. 62 , e202214880 (2023). • Mitsuki Ikeda, Zhiyan Zhang, Hidenori Goto, Ritsuko Eguchi, Yen-Fa Liao, Hirofumi Ishii, and Yoshihiro Kubozono*, “ Pressure Dependence of Superconductivity in a Charge-density-wave Superconductor Bi 2 Rh 3 Se 2 ”, Inorg. Chem. 62 , 7453 (2023). • Mitsuki Ikeda, Huan Li, Zhiyan Zhang, Yuki Yamamoto, Hidenori Goto, Ritsuko Eguchi, Hirofumi Ishii, Yen-Fa Liao, Yasuhiro Takabayashi, Koichi Hayashi, and Yoshihiro Kubozono*, “ Pressure Dependence of Superconductivity in Alkaline Earth Metal-doped FeSe: toward Completion of the Phase Diagram of Superconducting Transition Temperature Versus FeSe Layer Distance ”, Chem. Mater. 35 , 4338 (2023). ◎ Shen-Jing Ji, Li-Wen Cao, Peng Zhang, Guan-Bo Wang, Ying-Rui Lu, Nian-Tzu Suen*( 孫念祖 ), Sung-Fu Hung*( 洪崧富 ), and Hao Ming Chen*( 陳浩銘 ), “ Dealloying-induced Zeolite-like Metal Framework of AB 2 Laves Phase Intermetallic Electrocatalysts ”, J. Am. Chem. Soc. 145 , 17892 (2023). • Tatsuya Kato*, Koji Kimura, Shinya Hosokawa, Shinji Ando, Seishi Kashima, Yusuke Hashimoto, Naohisa Happo, Tomohiro Matsushita, Hirofumi Ishii, Kouichi Hayashi, “ Local Structure Analysis Around Y in Mg 99.7 Y 0.3 Single Crystal Using X-ray Fluorescence Holography ”, J. Electron Spectrosc. 262 , 147279 (2023). • Seunghwa Lee, You-Chiuan Chu, Lichen Bai, Hao Ming Chen, and Xile Hu* ( 胡喜樂 ), “ Operando Identification of a Side-on Nickel Superoxide Intermediate and the Mechanism of Oxygen Evolution on Nickel Oxyhydroxide ”, Chem Catalysis 3 , 100475 (2023). • Han Li, Qinjun Song, Sijie Wan, Ching-Wei Tung, Chengyuan Liu, Yang Pan, GuoQiang Luo, Hao Ming Chen*( 陳浩銘 ), Shaowen Cao*( 曹少文 ), Jiaguo Yu, and Lian Meng Zhang, “ Atomic Interface Engineering of Single-atom Pt/ TiO 2 -Ti 3 C 2 for Boosting Photocatalytic CO 2 Reduction ”, Small 19 , 2301711 (2023). • Chih-Ming Lin*( 林志明 ), Yu-Chin Tseng, Yi-Jia Tsai, Yu-Sheng Lin, Sheng- Rui Jian*( 簡賸瑞 ), Yu-Chun Chuang, and Jenh-Yih Juang*( 莊振益 ), “ Effects of Lattice Distortion and Amount of d Electrons on the Pressure-driven Structural Phase Transition in ZnO: A Comparative Study of V-, Mn-, and Co- doped ZnO ”, Appl. Phys. Lett. 123 , 062101 (2023). • Kuen-Song Lin*( 林錕松 ), Ndumiso Vukile Mdlovu, Ruey-Shin Juang* ( 莊瑞鑫 ), Mau-Tsu Tang, “ Fine Structural Characterization of Noble Metals in Washcoat of Motorcycle Three-way Converter Catalysts ”, J. Environ. Chem. Eng. 11 , 109530 (2023). • Yu-Hao Lin, Wan-Tien Huang, Yi-Ting Huang, Yi-Ni Jhang, Tsung-Ting Shih, Murat Yılmaz, and Ming-Jay Deng*( 鄧名傑 ), “ Evaluation of Polymer Gel Electrolytes for Use in MnO 2 Symmetric Flexible Electrochemical Supercapacitors ”, Polymers 15 , 3438 (2023). • Mingchuan Luo, Adnan Ozden, Ziyun Wang, Fengwang Li, Jianan Erick Huang, Sung-Fu Hung, Yuhang Wang, Jun Li, Dae-Hyun Nam, Yuguang C. Li, Yi Xu, Ruihu Lu, Shuzhen Zhang, Yanwei Lum, Yang Ren, Longlong Fan, Fei Wang, Hui-hui Li, Dominique Appadoo, Cao-Thang Dinh, Yuan Liu, Bin Chen, Joshua Wicks, Haijie Chen, David Sinton, and Edward H. Sargent*, “ Coordination Polymer Electrocatalysts Enable Efficient CO-to-acetate Conversion ”, Adv. Mater. 35 , 2209567 (2023). • Takeshi Nakagawa*, Martina Vrankić, Melita Menelaou, Raimundas Sereika, Dong Wang, Jianbo Zhang, Hirofumi Ishii, Nozomu Hiraoka, Yang Ding* ( 丁陽 ), “ Pressure-induced Valence Fluctuation in CsEuF 3 : From Divalent Eu Valence to Trivalent Eu Valence State ”, J. Phys. Chem. Solids 175 , 111202 (2023). • Weiyan Ni, Josephine Lederballe Meibom, Noor Ul Hassan, Miyeon Chang, You-Chiuan Chu, Anna Krammer, Songlan Sun, Yiwei Zheng, Lichen Bai, Wenchao Ma, Seunghwa Lee, Seongmin Jin, Jeremy S. Luterbacher, Andreas Schüler, Hao Ming Chen, William E. Mustain*, and Xile Hu*( 胡喜樂 ), “ Synergistic Interactions between PtRu Catalyst and Nitrogen-doped Carbon Support Boost Hydrogen Oxidation ”, Nat. Catal. 6 , 773 (2023).