NSRRC Activity Report 2023

152 NSRRC ACTIVITY REPORT 2023 “ Stabilizing Ruthenium Dioxide with Cationanchored Sulfate for Durable Oxygen Evolution in Proton-exchange Membrane Water Electrolyzers ”, Nat. Commun. 14 , 8093 (2023). • Thomas Yang, Dinesh Bhalothia, Hong-Wei Chang, Che Yan, Amisha Beniwal, You-Xun Chang, Shun-Chi Wu, Po-Chun Chen, Kuan-Wen Wang*( 王冠文 ), Sheng Dai*( 戴升 ), Tsan-Yao Chen*( 陳燦耀 ), “ Oxygen Vacancies Endow Atomic Cobalt-palladium Oxide Clusters with Outstanding Oxygen Reduction Reaction Activity ”, Chem. Eng. J. 454 , 140289 (2023). • Zhibo Yao, Shiqiang Liu, Honghong Liu, Yukun Ruan, Song Hong, Tai-Sing Wu, Leiduan Hao, Yun-Liang Soo, Pei Xiong, Molly Meng-Jung Li, Alex W. Robertson, Qineng Xia, Liang-Xin Ding*( 丁良鑫 ), and Zhenyu Sun* ( 孫振宇 ), “ Pre-adsorbed H-assisted N 2 Activation on Single-atom Cadmium-O 5 Decorated In 2 O 3 for Efficient NH 3 Electrosynthesis ”, Adv. Funct. Mater. 33 , 2209843 (2023). • Qing Yi, Songlin Wu*( 伍松林 ), Yunjia Liu, Ting-Shan Chan, Ying-Rui Lu, Narottam Saha, Gordon Southam, Longbin Huang*( 黄隆斌 ), “ Mineral Weathering of Iron Ore Tailings Primed by Acidithiobacillus Ferrooxidans and Elemental Sulfur Under Contrasting pH Conditions ”, Sci. Total Environ. 856 , 159078 (2023). • Qing Yi, Fang You, Zhen Li, Songlin Wu*( 伍松林 ), Ting-Shan Chan, Ying-Rui Lu, Lars Thomsen, Jian Wang, Yuanying Ma, Yunjia Liu, Lachlan Robertson, Gordon Southam, and Longbin Huang*( 黄隆斌 ), “ Elemental Sulfur and Organic Matter Amendment Drive Alkaline pH Neutralization and Mineral Weathering in Iron Ore Tailings Through Inducing Sulfur Oxidizing Bacteria ”, Environ. Sci. Technol. 57 , 21744 (2023). • Zhiyong Yu, Shengyao Lv, Qing Yao, Nan Fang, Yong Xu*( 徐勇 ), Qi Shao, Chih-Wen Pao, Jyh-Fu Lee, Guoliang Li, Li-Ming Yang*( 楊利明 ), and Xiaoqing Huang*( 黃小青 ), “ Low-coordinated Pd Site within Amorphous Palladium Selenide for Active, Selective and Stable H 2 O 2 Electrosynthesis ”, Adv. Mater. 35 , 2208101 (2023). • Yaqiong Zeng, Jian Zhao, Shifu Wang, Xinyi Ren, Yuanlong Tan, Ying-Rui Lu, Shibo Xi, Junhu Wang, Frédéric Jaouen*, Xuning Li*( 李旭寧 ), Yanqiang Huang, Tao Zhang, and Bin Liu*( 劉斌 ), “ Unraveling the Electronic Structure and Dynamics of the Atomically Dispersed Iron Sites in Electrochemical CO 2 Reduction ”, J. Am. Chem. Soc. 145 , 15600 (2023). • Haoyue Zhang, Lingling Wu, Ruohan Feng, Sihong Wang, Chia-Shuo Hsu, Yuanman Ni, Ashfaq Ahmad, Chaoran Zhang, Haofei Wu, Hao-Ming Chen, Wang Zhang, Yao Li, Pan Liu, and Fang Song*( 宋鈁 ), “ Oxygen Vacancies Unfold the Catalytic Potential of NiFe-layered Double Hydroxides by Promoting Their Electronic Transport for Oxygen Evolution Reaction ”, ACS Catalysis 13 , 6000 (2023). ◎ Jincheng Zhang, Qilun Wang, Chunyu Qiu, Liyong Gan, Jie Ding, Fuhua Li, Tian Wang, Yuhang Liu, Yucheng Wang, Huabing Tao, Sung-Fu Hung*( 洪崧富 ), Hongbin Yang*( 楊鴻斌 ), and Bin Liu*( 劉彬 ), “ Boosting Activity of Fe-N4 Sites in Single-Fe-atom Catalysts via S in the Second Coordination Sphere for Direct Methanol Fuel Cells ”, Cell Rep. Phys. Sci. 4 , 101330 (2023). • Yanping Zhu, Ke Fan, Chia-Shuo Hsu, Gao Chen, Changsheng Chen, Tiancheng Liu, Zezhou Lin, Sixuan She, Liuqing Li, Hanmo Zhou, Ye Zhu, Hao Ming Chen*( 陳浩銘 ), Haitao Huang*( 黃海濤 ), “ Supported Ruthenium Single-atom and Clustered Catalysts Outperform Benchmark Pt for Alkaline Hydrogen Evolution ”, Adv. Mater. 35 , 2301133 (2023). TLS 01C2 SWLS − X-ray Powder Diffraction • Dinesh Bhalothia, Shou-Shiun Yang, Che Yan, Amisha Beniwal, You-Xun Chang, Shun-Chi Wu, Po-Chun Chen, Kuan-Wen Wang, and Tsan-Yao Chen* ( 陳燦耀 ), “ Surface Anchored Atomic Cobalt-oxide Species Coupled with Oxygen Vacancies Boost the CO-production Yield of Pd Nanoparticles ”, Sustain. Energy Fuels 7 , 526 (2023). • Dinesh Bhalothia, Che Yan, Nozomu Hiraoka, Hirofumi Ishii, Yen-Fa Liao, Po-Chun Chen, Kuan-Wen Wang, Jyh-Pin Chou, Sheng Dai*( 戴升 ), and Tsan- Yao Chen*( 陳燦耀 ), “ Pt-Mediated Interface Engineering Boosts the Oxygen Reduction Reaction Performance of Ni Hydroxide-supported Pd Nanoparticles ”, ACS Appl. Mater. Interfaces 15 , 16177 (2023). • Dinesh Bhalothia, Sheng-Po Wang, Pei-You Chen, Han-Po Wu, Amisha Beniwal, Che Yan, Jyh-Fu Lee, Tsan-Yao Chen, and Po-Chun Chen*( 陳柏鈞 ), “ Configuration-dependent Oxygen Reduction Reaction Performance of Iridium- decorated Ni@Pd Nanocatalysts ”, J. Phys. Chem. C 127 , 9594 (2023). • Dinesh Bhalothia, Amisha Beniwal, Praveen Kumar Saravanan, Guo-Heng Huang, Mingxing Cheng, Ming-Wei Lin, Po-Chun Chen*( 陳柏均 ), and Tsan- Yao Chen*( 陳燦耀 ), “ Facile Surface Restructure by One-step Sub-millisecond Laser Exposure Pomotes the CO 2 Methanation Performance of Cobalt Oxide Supported Pd Nanoparticles with Copper-oxide Cluster Eecoration ”, Mater. Adv. 4 , 6578 (2023). • Ming-Hsien Chan, Bo-Gu Chen, Wen-Tse Huang, Ting-Yi Su, Michael Hsiao* ( 蕭宏昇 ), Ru-Shi Liu*( 劉如熹 ), “ Tunable Single-atom Nanozyme Catalytic System for Biological Applications of Therapy and Diagnosis ”, Mater. Today Adv. 17 , 100342 (2023). • Ming-Hsien Chan, Bo-Gu Chen, Chien-Hsiu Li, Wen-Tse Huang, Ting-Yi Su, Lichang Yin*( 尹利長 ), Michael Hsiao*( 蕭宏昇 ), and Ru-Shi Liu*( 劉如 熹 ), “ Amplification of Oxidative Stress by Lipid Surface-coated Single-atom Au Nanozymes for Oral Cancer Photodynamic Therapy ”, Nanoscale 15 , 15558 (2023). • Po-Ya Chang, Chung-Kai Chang, Yu-Chun Chuang, Bo-Hao Chen, Yen-Chung Lai, Hwo-Shuenn Sheu*( 許火順 ), “ In Situ Synchrotron PXRD Investigation of Fresh and Aged Equisetum Ramosissimum Desf. (Horsetail Grass) ”, J. Chin. Chem. Soc. 70 , 1009 (2023). • Bo-Hao Chen, Jun-Jia Xu, Wei-Ren Lai, Chung-Kai Chang, Jeng-Lung Chen, Jyh-Fu Lee, Jin-Ming Chen, Hwo-Shuenn Sheu, Jey-Jau Lee, Yoshiki Kubota, Ming-Hsi Chiang, Yasutaka Kitagawa*, Yu-Chun Chuang*( 莊裕鈞 ), I-Jui Hsu*( 許益瑞 ), “ Structure Determination and Magnetic Studies of Triazole Chelated Co(II) Coordination Polymers ”, J. Chin. Chem. Soc. 70 , 1187 (2023). • Guan-Ruei Chen, Mei-Ting Shih, Kuei-Bo Chen, and Chi-Shen Lee*( 李積琛 ), “ Synthesis and Characterization of Multinary Selenides A 4 B 10 Se 19 (A=Sn, Pb; B=Sb, Bi) ”, Z. Anorg. Allg. Chem. 649 , e202200271 (2023). • Hsi Chen, Yan-Cheng Chen, Hao-Wen Liu, Shu-Jui Chang, Cheng-Hung Liao, Senthil-Kumar Parthasarathi, Satish Bolloju, Yu-Ting Weng, Jyh-Fu Lee, Jin-Ming Chen, Hwo-Shuenn Sheu, Chih-Wen Pao), and Nae-Lih Wu*( 吳 乃立 ), “ A Boron-nitride Based Dispersive Composite Coating on Nickel-rich Layered Cathodes for Enhanced Cycle Stability and Safety ”, J. Mater. Chem. A 11 , 13309 (2023). • Kai-Yue Chen, Yu-Ting Liu, Jui-Ting Hung, Yi-Cheng Hsieh, Yu-Min Tzou* ( 鄒裕民 ), “ Synergism of Fe and Al Salts for the Coagulation of Dissolved Organic Matter: Structural Developments of Fe/Al-organic Matter Associations ”, Chemosphere 316 , 137737 (2023). • Mingzhe Chen*( 陳明哲 ), Jing Zhang, Jiliang Zhang, Binkai Yu, Limin Zhou, Yao Xiao, Xu Gao, Jin Xiao*( 肖晶 ), Chunsheng Li*( 李春生 ), Yan Sun*( 孫嬿 ), Huakun Liu, Shixue Dou, and Shulei Chou*( 術雷 ), “ Reactive Boride as a Multifunctional Interface Stabilizer for Garnet-type Solid Electrolyte in All- solid-state Lithium Batteries ”, Nanoscale 15 , 13076 (2023). • Wen-Chia Chen, Ruei-Ci Wang, Sheng-Kai Yu, Jheng-Liang Chen, Yu-Han Kao, Tzi-Yuan Wang, Po-Ya Chang, Hwo-Shuenn Sheu, Ssu-Ching Chen, Wei-Ren Liu, Ta-I Yang*( 楊大毅 ), and Hsuan-Chen Wu*( 吳亘承 ), “ Self-healable Spider Dragline Silk Materials ”, Adv. Funct. Mater. 33 , 2303571 (2023). • Liming Deng, Sung-Fu Hung, Sheng Zhao, Wen-Jing Zeng, Zih-Yi Lin, Feng Hu, Yaoyi Xie, Lijie Yin, Linlin Li, and Shengjie Peng*( 彭生杰 ), “ Unveiling Coordination Transformation for Dynamically Enhanced Hydrogen Evolution Catalysis ”, Energ. Environ. Sci. 16 , 5220 (2023). • Ming-Jay Deng*( 鄧名傑 ), Yu-Syuan Wu, “ 2.2 V Wearable Asymmetric Supercapacitors Based on Co Oxide//Mn Oxide Electrodes and a PVA-KOH- urea-LiClO 4 Alkaline Gel Electrolyte ”, J. Alloy. Compd. 945 , 169285 (2023). • Alexey Falin, Haifeng Lv, Eli Janzen, James H. Edgar, Rui Zhang, Dong Qian, Hwo-Shuenn Sheu, Qiran Cai, Wei Gan, Xiaojun Wu, Elton J. G. Santos, and Lu Hua Li*, “ Anomalous Isotope Effect on Mechanical Properties of Single Atomic Layer Boron Nitride ”, Nat. Commun. 14 , 5331 (2023). • Jia-Yu Hsu, Ren-Jei Chung, Yen-Ling Kuo, Chun Che Lin, Natalia Majewska, Dominik Kreft, Sebastian Mahlik*, and Mu-Huai Fang*( 方牧懷 ), “ Concentration-induced Hetero-valent Partial-inverse Occupation of Infrared Phosphor ”, Adv. Opt. Mater. 11 , 2300121 (2023). • Haoliang Huang, Yu-Chung Chang, Yu-Cheng Huang, Lili Li, Alexander C. Komarek, Liu Hao Tjeng, Yuki Orikasa, Chih-Wen Pao, Ting-Shan Chan, Jin-Ming Chen, Shu-Chih Haw, Jing Zhou, YifengWang, Hong-Ji Lin, Chien-Te Chen, Chung-Li Dong, Chang-Yang Kuo, Jian-Qiang Wang, Zhiwei Hu, and Linjuan Zhang*( 張林娟 ), “ Unusual Double Ligand Holes as Catalytic Active Sites in LiNiO 2 ”, Nat. Commun. 14 , 2112 (2023). • Jheng-Yi Huang, Ching-Yun Cheng, Yan-Ming Lai, Kevin Iputera, Ren-Jei Chung*( 鍾仁傑 ), and Ru-Shi Liu*( 劉如熹 ), “ Engineering Cathode-electrolyte Interface of High-voltage Spinel LiNi 0.5 Mn 1.5 O 4 via Halide Solid-state Electrolyte Coating ”, ACS Appl. Mater. Interfaces 15 , 40648 (2023). • Wei-Hsiang Huang, Chin-Jung Lin, Tsung-Han Huang, Chia-Yu Chang, Shu-Chih Haw, Hwo-Shuenn Sheu, Shih-Yun Chen, Chung-Li Dong, Krishna Kumar, Bing Joe Hwang*( 黃炳照 ), Wei-Nien Su*( 蘇威年 ), Chi-Liang Chen* ( 陳啟亮 ), “ Mechanistic Study for Enhanced Photocatalytic Degradation of Acetaminophen by Fe(III) Doped TiO 2 Hollow Submicrospheres ”, Appl. Surf. Sci. 611 , 155634 (2023). • Shi-Kai Jiang, Sheng-Chiang Yang, Wei-Hsiang Huang, Hung-Yi Sung, Ruo- Yun Lin, Jhao-Nan Li, Bo-Yang Tsai, Tripti Agnihotri, Yosef Nikodimos, Chia- Hsin Wang, Shawn D. Lin, Chun-Chieh Wang, She-Huang Wu*( 吳溪煌 ), Wei- Nien Su*( 蘇威年 ), and Bing Joe Hwang*( 黃炳照 ), “ Enhancing the Interfacial Stability Between Argyrodite Sulfide-based Solid Electrolytes and Lithium Electrodes Through CO 2 Adsorption ”, J. Mater. Chem. A 11 , 2910 (2023). • Chusnul Khotimah, Fu-Ming Wang*( 王復民 ), Margret Wohlfahrt-Mehrens,