NSRRC Activity Report 2023

Appendix 149 Hu, Li-Ming Yang*( 楊利明 ), Xiaoqing Huang, Qi Shao*( 邵琪 ), and Jianmei Lu*( 路建美 ), “ Face-centered Cubic Ruthenium Nanocrystals with Promising Thermal Stability and Electrocatalytic Performance ”, ACS Catalysis 13 , 11023 (2023). ◎ Trakarn Yimtrakarn, Yi-Chih Liao, Ahmed Sanin MV, Jeng-Lung Chen, Yu- Chun Chuang, Nuttapol Lerkkasemsan, Watchareeya Kaveevivitchai*, “ Mn-Fe Prussian Blue Analogue as Low-cost Robust Cathode for Non-aqueous Zn-ion Batteries ”, Mater. Today Comm. 34 , 105231 (2023). • Hanzhi Yu, Shangqian Zhu, Yixin Hao, Yu-Ming Chang, Linlin Li, Jun Ma, Han-Yi Chen, Minhua Shao, Shengjie Peng*( 彭生杰 ), “ Modulating Local Interfacial Bonding Environment of Heterostructures for Energy- saving Hydrogen Production at High Current Densities ”, Adv. Funct. Mater. 33 , 2212811 (2023). • Zhiyong Yu, Shengyao Lv, Qing Yao, Nan Fang, Yong Xu*( 徐勇 ), Qi Shao, Chih-Wen Pao, Jyh-Fu Lee, Guoliang Li, Li-Ming Yang*( 楊利明 ), and Xiaoqing Huang*( 黃小青 ), “ Low-coordinated Pd Site within Amorphous Palladium Selenide for Active, Selective and Stable H 2 O 2 Electrosynthesis ”, Adv. Mater. 35 , 2208101 (2023). • Amelia T. Yuan, Lijia Liu, Lo-Yueh Chang, and Martin J. Stillman*, “ Xenobiotic Bi 3+ Coordination by Cysteine-Rich Metallothionein3 Reveals a Cooperatively Formed Thiolate-Sharing Bi 2 S 5 Cluster ”, Inorg. Chem. 62 , 13011 (2023). • Changhong Zhan, Lingzheng Bu, Haoran Sun, Xingwei Huang, Zhipeng Zhu, Tang Yang, Haibin Ma, Leigang Li, Yucheng Wang*( 王宇成 ), Hongbo Geng, Weizhen Wang, Huaze Zhu, Chih-Wen Pao, Qi Shao, Zhiqing Yang*( 楊志卿 ), Wei Liu*( 劉偉 ), Zhaoxiong Xie, and Xiaoqing Huang*( 黃小青 ), “ Medium/ High-entropy Amalgamated Core/Shell Nanoplate Achieves Efficient Formic Acid Catalysis for Direct Formic Acid Fuel Cell ”, Angew. Chem. Int. Edit. 62 , e202213783 (2023). • Juntao Zhang, Maofeng Cao, Xiaotong Li, Yong Xu*( 徐勇 ), Wei Zhao, Ligang Chen*( 陳立鋼 ), Yu-Chung Chang, Chih-Wen Pao, Zhiwei Hu, Xiaoqing Huang*( 黃小青 ), “ Kinetic-modulated Crystal Phase of Ru for Hydrogen Oxidation ”, Small 19 , 2207038 (2023). • Juntao Zhang, Xiaozhi Liu, Yujin Ji, Xuerui Liu, Dong Su*( 蘇東 ), Zhongbin Zhuang, Yu-Chung Chang, Chih-Wen Pao), Qi Shao*( 邵琪 ), Zhiwei Hu, and Xiaoqing Huang*( 黃小青 ), “ Atomic-thick Metastable Phase RhMo Nanosheets for Hydrogen Oxidation Catalysis ”, Nat. Commun. 14 , 1761 (2023). • Juntao Zhang, Xiaozhi Liu, Ligang Chen, Maofeng Cao, Xiaotong Li, Dong Su, Zhiwei Hu, Yong Xu*( 徐勇 ), Xiaoqing Huang*( 黃小青 ), “ Alkali Cation- controlled Synthesis of Metastable Ru Phase ”, Sci. Bull. 68 , 2924 (2023). • Qiao Zhang, Hsin Jung Tsai, Fuhua Li, Zhiming Wei, Qinye He, Jie Ding, Yuhang Liu, Zih-Yi Lin, Xiaoju Yang, Zhaoyang Chen, Fangxin Hu, Xuan Yang, Qing Tang*( 唐青 ), Hong Bin Yang*( 楊鴻斌 ), Sung-Fu Hung*( 洪崧富 ), and Yueming Zhai*( 翟月明 ), “ Boosting the Proton-coupled Electron Transfer via Fe-P Atomic Pair for Enhanced Electrochemical CO 2 Reduction ”, Angew. Chem. Int. Edit. 62 , e202311550 (2023). ◎ Shumin Zhang, Feipeng Zhao, Jiatang Chen, Jiamin Fu, Jing Luo, SandaminiH. Alahakoon, Lo-YuehChang, Renfei Feng, Mohsen Shakouri, Jianwen Liang, Yang Zhao, Xiaona Li, Le He, YiningHuang, Tsun-Kong Sham*( 岑俊江 ), and Xueliang Sun*( 孫學良 ), “ A Family of Oxychloride Amorphous Solid Electrolytes for Long-cycling All-solid-state Lithium Batteries ”, Nat. Commun. 14 , 3780 (2023). • Yi Zhang, Mengwen Wang, Wenxiang Zhu, Miaomiao Fang, Mengjie Ma, Fan Liao*( 廖凡 ), Hao Yang*( 楊昊 ), Tao Cheng, Chih-Wen Pao, Yu-Chung Chang, Zhiwei Hu, Qi Shao*, Mingwang Shao*( 邵名望 ), and Zhenhui Kang* ( 康振輝 ), “ Metastable Hexagonal Phase SnO 2 Nanoribbons with Active Edge Sites for Efficient Hydrogen Peroxide Electrosynthesis in Neutral Media ”, Angew. Chem. Int. Edit. 62 , e202218924 (2023). • Sheng Zhao, Lijie Yin, Liming Deng, Junnan Song, Yu-Ming Chang, Feng Hu, Hui Wang, Han-Yi Chen, Linlin Li, and Shengjie Peng*( 彭生杰 ), “ Inheritable Organic-inorganic Hybrid Interfaces with π-d Electron Coupling for Robust Electrocatalytic Hydrogen Evolution at High-current-densities ”, Adv. Funct. Mater. 33 , 2211576 (2023). TPS 45A Submicron Soft X-ray Spectroscopy • Shanquan Chen, Jhong-Yi Chang, Qinghua Zhang, Qiuyue Li, Ting Lin, Fanqi Meng, Haoliang Huang, Yangyang Si, Shengwei Zeng, Xinmao Yin, My Ngoc Duong, Yalin Lu, Lang Chen, Er-Jia Guo, Hanghui Chen, Chun-Fu Chang, Chang-Yang Kuo*( 郭昌洋 ), and Zuhuang Chen*( 陳祖煌 ), “ Spin State Disproportionation in Insulating Ferromagnetic LaCoO 3 Epitaxial Thin Films ”, Adv. Sci. 10 , 2303630 (2023). • Brandon Faceira, Lionel Teulé-Gay, Jade Le Hébel, Christine Labrugère- Sarroste, Fabienne Ibalot, Hou-Yi Huang, Yu-Cheng Huang, Chung-Li Dong, Jean-Paul Salvetat, Mario Maglione, and Aline Rougier*, “ Origin of the Memory Effect in Electrochromic Sputtered WO 3 Films: Composition, Structure, or Morphology? ”, Adv. Mater. Interfaces 10 , 2300549 (2023). • Chih-Ying Huang, Hung-Min Lin, Chun-Hao Chiang, Hsin-An Chen, Ting- Ran Liu, Deepak Vishnu S. K, Jau-Wern Chiou*( 邱昭文 ), Raman Sankar*, Huang-Ming Tsai, Way-Faung Pong*( 彭維鋒 ), and Chun-Wei Chen* ( 陳俊維 ), “ Manipulating Spin Exchange Interactions and Spin-selected Electron Transfers of 2D Metal Phosphorus Trisulfide Crystals for Efficient Oxygen Evolution Reaction ”, Adv. Funct. Mater. 33 , 2305792 (2023). • Lun Jin*, Haozhe Wang, Xianghan Xu, Danrui Ni, Chen Yang, Yu-Chieh Ku, Cheng-En Liu, Chang-Yang Kuo, Chun-Fu Chang, Raimundas Sereika, Wenli Bi, Weiwei Xie, and Robert J. Cava*, “ Hidden Hydroxides in KOH-grown BaNiO 3 Crystals: A Potential Link to Their Catalytic Behavior ”, Chem. Mater. 35 , 9434 (2023). • Yu-Hong Lai, Pao-Wen Shao, Chang-Yang Kuo, Cheng-En Liu, Zhiwei Hu, Chen Luo, Kai Chen, Florin Radu, Yong-Jyun Wang, Junding Zheng, Chungang Duan, Chun-Fu Chang, Li Chang, Yi-Chun Chen, Sang-Wook Cheong, Ying-Hao Chu*( 朱英豪 ), “ Quasi-static Modulation of Multiferroic Properties in Flexible Magnetoelectric Cr 2 O 3 /Muscovite Heteroepitaxy ”, Acta Mater. 243 , 118509 (2023). • Jiann-Shing Lee, Shih-Min Hung, Chun-Rong Lin, Chi-Liang Chen, Jau-Wern Chiou, Chih-Yu Hua, Huang-Ming Tsai, Way-Faung Pong, Chien-Te Chen, Wen-Bin Wu*( 吳文斌 ), and Jiunn Chen*( 陳駿 ), “ Polarized Hole Injection- induced Magnetic Enhancement in Carbon-encapsulated Cobalt Ferrite Nanoparticles ”, J. Phys. Chem. C 127 , 17978 (2023). • Andrea Marino, Denise S. Christovam, Chun-Fu Chang, Johannes Falke, Chang-Yang Kuo, Chi-Nan Wu, Martin Sundermann, Andrea Amorese*, Hlynur Gretarsson, Eric Lee-Wong, Camilla M. Moir, Yuhang Deng, M. Brian Maple, Peter Thalmeier, Liu Hao Tjeng, and Andrea Severing, “ Fe Substitution in URu 2 Si 2 : Singlet Magnetism in an Extended Doniach Phase Diagram ”, Phys. Rev. B 108 , 085128 (2023). • Saravanakumar Muthusamy, Palani Sabhapathy, Putikam Raghunath, Amr Sabbah, Yu-Chung Chang, Vimal Krishnamoorthy, Thi-Thong Ho, Jau-Wern Chiou, Ming-Chang Lin, Li-Chyong Chen*( 林麗瓊 ), and Kuei-Hsien Chen* ( 陳貴賢 ), “ Mimicking Metalloenzyme Microenvironments in the Transition Metal-single Atom Catalysts for Electrochemical Hydrogen Peroxide Synthesis in an Acidic Medium ”, Small Methods 7 , 2300234 (2023). • M. Okawa*, D. Takegami, D. S. Christovam, M. Ferreira-Carvalho, C.-Y. Kuo, C. T. Chen, T. Miyoshino, K. Takasu, T. Okuda, C. F. Chang, L. H. Tjeng, and T. Mizokawa*, “ Linear Dichroic X-ray Absorption Response of Ti-Ti Dimers along the c Axis in Ti 2 O 3 upon Mg Substitution ”, Phys. Rev. B 108 , 195108 (2023). • V. M. Pereira, A. Meléndez-Sans, C. F. Chang, C.-Y. Kuo, C. T. Chen, L. H. Tjeng, and S. G. Altendorf, “ Epitaxial HoN Thin Films: An Investigation of the Structural, Electronic, and Magnetic Properties ”, Phys. Rev. Mater. 7 , 124405 (2023). ◎ D. Takegami, A. Tanaka, S. Agrestini*, Z. Hu, J. Weinen, M. Rotter, C. Schüßler-Langeheine*, T. Willers, T. C. Koethe, T. Lorenz, Y. F. Liao, K. D. Tsuei, H.-J. Lin, C. T. Chen, and L. H. Tjeng, “ Paramagnetic LaCoO 3 : A Highly Inhomogeneous Mixed Spin-state System ”, Phys. Rev. X 13 , 011037 (2023). • Daisuke Takegami*, Zhiwei Hu, Johannes Falke, Anna Meléndez-Sans, Cheng-En Liu, Chun-Fu Chang, Chang-Yang Kuo, Chien-Te Chen, Hanjie Guo, Alexander Komarek, Arata Tanaka, Sylvie Hébert, and Liu Hao Tjeng*( 莊鎏豪 ), “ Electronic Structure of the High-spin Co 4+ System Ba 2 CoO 4 ”, Z. Anorg. Allg. Chem. 649 , e202300077 (2023). • Hailin Wang, Haoliang Huang, Yanpeng Feng, Yu-Chieh Ku, Cheng-En Liu, Shanquan Chen, Alan Farhan, Cinthia Piamonteze, Yalin Lu, Yunlong Tang, Jun Wei, Lang Chen, Chun-Fu Chang, Chang-Yang Kuo*( 郭昌洋 ), and Zuhuang Chen*( 陳祖煌 ), “ Enhanced Exchange Bias in Epitaxial High-entropy Oxide Heterostructures ”, ACS Appl. Mater. Interfaces 15 , 58643 (2023). • Priyanka L. Yadav, Abhijeet R. Shelke, Hsiao-Tsu Wang, Kuan-Hung Chen, Wei- Xuan Lin, Chin-Wei Li, Mei-Yu Chen, Ping-Hung Yeh, Chung-Li Dong* ( 董崇禮 ), Mohammad Qorbani, Yu-Cheng Huang, Jau-Wern Chiou, Huang- Ming Tsai, Prakash M. Kadam, Kuei-Hsien Chen, Li-Chyong Chen*( 林麗瓊 ), and Way-Faung Pong*( 彭維鋒 ), “ Mn 3+ e g Configuration and Electron Transfer in Na-incorporating αMnO 2 to Improve Electrochemical Supercapacitor: An In Situ and Ex Situ X-ray Absorption Spectroscopic Investigation ”, ACS Appl. Energy Mater. 6 , 6443 (2023). TLS 01B1 SWLS − X-ray Microscopy (PRT 75%) ◎ Teshome Assefa Nigatu, Hailemariam Kassa Bezabh, Shi-Kai Jiang, Bereket Woldegbreal Taklu, Yosef Nikodimos, Sheng-Chiang Yang, She-Huang Wu, Wei-Nien Su*( 蘇威年 ), Chun-Chen Yang*( 楊純誠 ), Bing Joe Hwang* ( 黃炳照 ), “ An Anode-free Aqueous Hybrid Batteries Enabled by In-situ Cu/ Sn/Zn Alloy Formation on Pure Cu Substrate ”, Electrochim. Acta 443 , 141883 (2023). ◎ Hailemariam Kassa Bezabh, Jeng-Chian Chiou, Teshome Assefa Nigatu, Teklay Mezgebe Hagos, Shi-Kai Jiang, Yosef Nikodimos, Bereket Woldegbreal Taklu, Meng-Che Tsai, Wei-Nien Su*( 蘇威年 ), and Bing Joe Hwang*( 黃炳照 ), “ In-