NSRRC Activity Report 2023

148 NSRRC ACTIVITY REPORT 2023 Singlets State Formed by Two-step Oxidation for Triggering Water Oxidation Under Operando Conditions ”, Nat. Commun. 14 , 529 (2023). • Huiping Peng, Hongcen Yang, Jiajia Han*( 韓佳甲 ), Xiaozhi Liu, Dong Su, Tang Yang, Shangheng Liu, Chih-Wen Pao, Zhiwei Hu, Qiaobao Zhang, Yong Xu*( 徐勇 ), Hongbo Geng, and Xiaoqing Huang*( 黃小青 ), “ Defective ZnIn 2 S 4 Nanosheets for Visible-light and Sacrificial-agent-free H 2 O 2 Photosynthesis via O 2 /H 2 O Redox ”, J. Am. Chem. Soc. 145 , 27757 (2023). • Xianyun Peng, Rui Zhang, Yuying Mi, Hsiao-Tsu Wang, Yu-Cheng Huang, Lili Han*, Ashley R. Head, Chih-Wen Pao, Xijun Liu, Chung-Li Dong, Qian Liu, Shusheng Zhang*( 張書勝 ), Way-Faung Pong, Jun Luo, and Huolin L. Xin*, “ Disordered Au Nanoclusters for Efficient Ammonia Electrosynthesis ”, ChemSusChem 16 , e202201385 (2023). • Yu-Ren Peng, Shin-Yi Tang, Tzi-Yi Yang, Paul Albert Sino, Yuan-Chun Chen, Mayur Chaudhary, Chieh-Ting Chen, Ruei-Hong Cyu, Chia-Chen Chung, Bing-Ni Gu, Ming-Jing Liu, Che-Hao Hsu, Hung-Yi Huang, Ling Lee, Shu-Chi Wu, Yu-Yi Jen, You-Song Cheng, Chi-Chang Hu, Wen-Chien Miao, Hao-Chung Kuo, and Yu-Lun Chueh*( 闕郁倫 ), “ Design of Electrocatalytic Janus WSeS/ WSe 2 Heterostructure Nanowall Electrodes with High Selectivity and Faradaic Efficiency for Nitrogen Reduction ”, Adv. Energy Mater. 13 , 2301979 (2023). • P Prabhu, Viet-Hung Do, Chun Kuo Peng, Huimin Hu, San-Yuan Chen, Jin-Ho Choi*, Yan-Gu Lin*( 林彥谷 ), and Jong-Min Lee*, “ Oxygen-bridged Stabilization of Single Atomic W on Rh Metallenes for Robust and Efficient pH- universal Hydrogen Evolution ”, ACS Nano 17 , 10733 (2023). • Veeramani Rajendran, Kuan-Chun Chen, Wen-Tse Huang, Mikołaj Kamiński, Maciej Grzegorczyk, Sebastian Mahlik, Grzegorz Leniec, Kuang-Mao Lu, Da- Hua Wei*( 魏大華 ), Ho Chang*( 張合 ), and Ru-Shi Liu*( 劉如熹 ), “ Unraveling Luminescent Energy Transfer Pathways: Futuristic Approach of Miniature Shortwave Infrared Light-emitting Diode Design ”, ACS Energ. Lett. 8 , 2395 (2023). • Wai-Tung Shiu, Xincheng Li, Lo-Yueh Chang, Jeng-Lung Chen, Yung-Yang Lin, Bi-Hsuan Lin, George E. Sterbinsky, Tianpin Wu, John A. McLeod, Lijia Liu*( 劉儷佳 ), “ The Influence of Hydrothermal Synthesis Temperature on the Electronic Structure and Luminescence Property of Cr-doped ZnGa 2 O 4 Nanoparticles ”, J. Lumin. 263 , 120113 (2023). • Hui-Ying Tan, Sheng-Chih Lin, Jiali Wang*( 王佳力 ), Jui-Hsien Chen, Chia-Jui Chang, Cheng-Hung Hou, Jing-Jong Shyue, Tsung-Rong Kuo, and Hao Ming Chen*( 陳浩銘 ), “ Reversibly Adapting Configuration in Atomic Catalysts Enables Efficient Oxygen Electroreduction ”, J. Am. Chem. Soc. 145 , 27054 (2023). • Aekkacha Tananonchai, Mau-Tsu Tang, Chih-Wen Pao, Pantawat Sampanpanish, Waraporn Tanthanuch*, Somchai Tancharakorn*, “ The Study of EDTA Enhanced Cd Accumulation and Formation in Napier Grass Using Synchrotron μX-ray Fluorescence Imaging and X-ray Absorption Spectroscopy ”, Radiat. Phys. Chem. 207 , 110851 (2023). • Korawich Trangwachirachai, I-Ting Kao, Wei-Hsiang Huang Chi-Liang Chen, and Yu-Chuan Lin*( 林裕川 ), “ Co-activation of Methane and Nitrogen to Acetonitrile over MoC x /Al 2 O 3 Catalysts ”, Catal. Sci. Technol. 13 , 5248 (2023). • Yi-Ting Tsai, Natalia Majewska, Mikołaj Kamiński, Bi-Hsuan Lin, Sebastian Mahlik*, and Mu-Huai Fang*( 方牧懷 ), “ Hidden Hexavalent Chromium Ions with Subtle Structural Evolution in Near-infrared Phosphors ”, ACS Appl. Mater. Interfaces 15 , 49379 (2023). • I-Hsiang Tseng*( 曾怡享 ), Yu-Hsuian Yang, Yi-Ting Chen, and Liang-Ching Hsu, “ Tailoring Copper Chemical Status and Hydrophobicity of Biomimetic Photocatalytic Films for Carbon Dioxide Conversion ”, ACS Appl. Mater. Interfaces 15 , 5038 (2023). • Yu-Ting Tseng, Vladimir Pelmenschikov*, Linda Iffland-Mühlhaus, Donato Calabrese, Yu-Che Chang, Konstantin Laun, Chih-Wen Pao, Ilya Sergueev, Yoshitaka Yoda, Wen-Feng Liaw, Chien-Hong Chen*( 陳建宏 ), I-Jui Hsu* ( 許益瑞 ), Ulf-Peter Apfel*, Giorgio Caserta*, Lars Lauterbach*, and Tsai- Te Lu*( 魯才德 ), “ Substrate-gated Transformation of a Pre-catalyst into an Iron-hydride Intermediate [(NO) 2 (CO)Fe(μ-H)Fe(CO)(NO) 2 ] − for Catalytic Dehydrogenation of Dimethylamine Borane ”, Inorg. Chem. 62 , 769 (2023). • Kuang-Chih Tso, Yi-Chieh Hsieh, Jyh-Fu Lee), Chih-Wen Pao, Po-Chun Chen, Jun Ohta and Pu-Wei Wu*( 吳樸偉 ), “ Time-resolved XAS Studies Reveal Sequential Oxidative-reductive Formation of Na-doped Iridium Oxide Films with Enhanced Bio-stimulating Performance ”, J. Mater. Chem. C 11 , 1979 (2023). • Truong-Giang Vo, Giang-Son Tran, Chao-Lung Chiang, Yan-Gu Lin, Huai- En Chang, Hsuan-Hung Kuo, Chia-Ying Chiang*( 江佳穎 ), and Yung-Jung Hsu*( 徐雍鎣 ), “ Au@NiS x Yolk@Shell Nanostructures as Dual-functional Electrocatalysts for Concomitant Production of Value-added Tartronic Acid and Hydrogen Fuel ”, Adv. Funct. Mater. 33 , 2209386 (2023). • Dongdong Wang, Zhiwen Chen, Yujie Wu, Yu-Cheng Huang, Li Tao*( 陶李 ), Jun Chen, Chung-Li Dong, Chandra Veer Singh, Shuangyin Wang*( 王雙印 ), “ Structurally Ordered High-entropy Intermetallic Nanoparticles with Enhanced C-C Bond Cleavage for Ethanol Oxidation ”, SmartMat 4 , e1117 (2023). • Kuangye Wang, Ling Lee, Sueh Liang Loo, Tzu-Yi Yang, Chieh-Ting Chen, Tzu-Wen Kuo, Jeng-Lung Chen), Hao-chung Kuo, and Yu-Lun Chueh* ( 闕郁倫 ), “ Controllable Vertical Nitrogen Doping in Nanoscaled Molybdenum Diselenide Films for Selective Sensing of NH 3 and NO 2 Gases ”, ACS Appl. Nano Mater. 6 , 5336 (2023). • Kuncan Wang, Yuanmin Zhu, Meng Gu, Zhiwei Hu, Yu-Chung Chang, Chih-Wen Pao, Yong Xu*( 徐勇 ), Xiaoqing Huang*( 黃小青 ), “ A Derivative of ZnIn 2 S 4 Nanosheet Supported Pd Boosts Selective CO 2 Hydrogenation ”, Adv. Funct. Mater. 33 , 2215148 (2023). • Luqi Wang, Li Song, Zhenyu Yang, Yu-Ming Chang, Feng Hu, Lei Li*( 李雷 ), Linlin Li*( 李林林 ), Han-Yi Chen, and Shengjie Peng*( 彭生杰 ), “ Electronic Modulation of Metal-organic Frameworks by Interfacial Bridging for Efficient pH-universal Hydrogen Evolution ”, Adv. Funct. Mater. 33 , 2210322 (2023). • Luqi Wang, Zipeng Xu, Chun-Han Kuo, Jian Peng, Feng Hu, Linlin Li, Han-Yi Chen, Jiazhao Wang, and Shengjie Peng*( 彭生杰 ), “ Stabilizing Low-valence Single Atoms by Constructing Metalloid Tungsten Carbide Supports for Efficient Hydrogen Oxidation and Evolution ”, Angew. Chem. Int. Edit. 62 , e202311937 (2023). • Xiaoyu Wang, Wenhuai Li, Chuan Zhou*, Meigui Xu, Zhiwei Hu, Chih-Wen Pao, Wei Zhou*( 周嵬 ), and Zongping Shao*( 邵宗平 ), “ Enhanced Proton Conduction with Low Oxygen Vacancy Concentration and Favorable Hydration for Protonic Ceramic Fuel Cells Cathode ”, ACS Appl. Mater. Interfaces 15 , 1339 (2023). • Xuchun Wang, Yu Liu, Xing-Yu Ma, Lo-Yueh Chang, Qixuan Zhong, Qi Pan, Zhiqiang Wang, Xiaolei Yuan, Muhan Cao, Fenglei Lyu, Yaoyue Yang*( 陽耀月 ), Jinxing Chen*( 陳金星 ), Tsun-Kong Sham*( 岑俊江 ), and Qiao Zhang* ( 張橋 ), “ The Role of Bismuth in Suppressing the CO Poisoning in Alkaline Methanol Electrooxidation: Switching the Reaction from the CO to Formate Pathway ”, Nano Lett. 23 , 685 (2023). • Xunlu Wang, Ruguang Ma*( 馬汝廣 ), Shanlin Li, Mengmeng Xu, Lijia Liu, Yihan Feng, Tiju Thomas, Minghui Yang*( 楊明輝 ), and Jiacheng Wang* ( 王家成 ), “ In Situ Electrochemical Oxyanion Steering of Water Oxidation Electrocatalysts for Optimized Activity and Stability ”, Adv. Eng. Mater. 13 , 2300765 (2023). • Daixing Wei, Yiqing Wang, Chung-Li Dong, Zhengqi Zhang, Xinyu Wang, Yu- Cheng Huang, Yuchuan Shi, Xiaoli Zhao, Jialin Wang, Ran Long, Yujie Xiong, Fan Dong, Mingtao Li, Shaohua Shen*( 沈少華 ), “ Decrypting the Controlled Product Selectivity over Ag-Cu Bimetallic Surface Alloys for Electrochemical CO 2 Reduction ”, Angew. Chem. Int. Edit. 62 , e202217369 (2023). • Xiaoxiao Wei, Yingying Liu, Xiaorong Zhu, Shuowen Bo, Lei Xiao, Chen Chen, Ta Thi Thuy Nga, Yuanqing He, Mengyi Qiu, Chao Xie, Dongdong Wang, Qinghua Liu, Fan Dong, Chung-Li Dong, Xian-Zhu Fu, Shuangyin Wang* ( 王雙印 ), “ Dynamic Reconstitution Between Copper Single atoms and Clusters for Electrocatalytic Urea Synthesis ”, Adv. Mater. 35 , 2300020 (2023). • Xinhao Wu, Yanan Guo, Yuxing Gu, Fenghua Xie, Mengran Li, Zhiwei Hu, Hong-Ji Lin, Chih-Wen Pao, Yu-Cheng Huang, Chung-Li Dong, Vanessa K. Peterson, Ran Ran, Wei Zhou*( 周嵬 ), Zongping Shao*( 邵宗平 ), “ In Operando-formed Interface Between Silver and Perovskite Oxide for Efficient Electroreduction of Carbon Dioxide to Carbon Monoxide ”, Carbon Energy 5 , e278 (2023). • Dongsheng Xia, Xuan Tang, Sheng Dai*( 戴升 ), Rile Ge, Alexander Rykov, Junhu Wang, Tzu-Hsi Huang, Kuan-Wen Wang, Yinping Wei, Kai Zhang, Jia Li, Lin Gan*( 干林 ), and Feiyu Kang*( 康飛宇 ), “ Ultrastable Fe-N-C Fuel Cell Electrocatalysts by Eliminating Non-coordinating Nitrogen and Regulating Coordination Structures at High Temperatures ”, Adv. Mater. 35 , 2204474 (2023). • Lifeng Xu, Shi Chen, Yuefeng Su*( 蘇岳鋒 ), Xing Shen, Jizhuang He, Maxim Avdeev, Wang Hay Kan*( 簡宏希 ), Bin Zhang, Weifeng Fan, Lai Chen, Duanyun Cao, Yun Lu, Lian Wang, Meng Wang, Liying Bao, Liang Zhang, Ning Li*( 李寧 ), and Feng Wu, “ Novel Low-strain Layered/Rocksalt Intergrown Cathode for High-energy Li-Ion Batteries ”, ACS Appl. Mater. Interfaces 15 , 54559 (2023). • Zichen Xu, Yuanjuan Jiang, Jeng-Lung Chen, and Ryan Yeh-Yung Lin*( 林燁雍 ), “ Heterostructured Ultrathin Two-dimensional Co-FeOOH Nanosheets@1D Ir-Co(OH)F Nanorods for Efficient Electrocatalytic Water Splitting ”, ACS Appl. Mater. Interfaces 15 , 16702 (2023). • Dongping Xue, Pengfei Yuan, Su Jiang, Yifan Wei, Ying Zhou, Chung-Li Dong, Wenfu Yan, Shichun Mu, Jia-Nan Zhang*( 張佳楠 ), “ Altering the Spin State of Fe-N-C through Ligand Field Modulation of Single-atom Sites Boosts the Oxygen Reduction Reaction ”, Nano Energy 105 , 108020 (2023). • Tang Yang, Li Lin, Ximeng Lv, Hongcen Yang, Huishu Feng, Zhongliang Huang, Jiwei Li, Chih-Wen Pao, Zhiwei Hu, Changhong Zhan, Yong Xu* ( 徐勇 ), Lan-Sun Zheng, Feng Jiao*, and Xiaoqing Huang*( 黃小青 ), “ Interfacial Synergy between the Cu Atomic Layer and CeO 2 Promotes CO Electrocoupling to Acetate ”, ACS Nano 17 , 8521 (2023). • Qing Yao, Sheng-Yao Lv, Zhiyong Yu, Yu-Chung Chang, Chih-Wen Pao, Zhiwei