NSRRC Activity Report 2022

146 NSRRC ACTIVITY REPORT 2022 Wong*( 黃國賢 ), and T. W. B. Lo*( 勞子桓 ), “ Atomically Precise Bimetallic Metal Ensembles with Tailorable Synergistic Effects ”, Cell Rep. Phys. Sci. 3 , 100850 (2022). • T.-Y. Chen, H. V. Thang, T.-Y. Yi, S.-C. Huang, C.-C. Lin, Y.-M. Chang, P.-L. Chen, M.-H. Lin, J.-F. Lee, H.-Y. T. Chen*( 陳馨怡 ), C.-C. Hu*( 胡啟章 ), and H.-Y. Chen*( 陳翰儀 ), “ Operando X-ray Studies of Ni-containing Heteropolyvanadate Electrode for High-energy Lithium-ion Storage Applications ”, ACS Appl. Mater. Interfaces 14 , 52035 (2022). • J. Dai, Y. Zhu*( 朱印龍 ), Y. Chen, X. Wen, M. Long, X. Wu, Z. Hu, D. Guan, X. Wang, C. Zhou, Q. Lin, Y. Sun, S.-C. Weng, H. Wang, W. Zhou, and Z. Shao* ( 邵宗平 ), “ Hydrogen Spillover in Complex Oxide Multifunctional Sites Improves Acidic Hydrogen Evolution Electrocatalysis ”, Nat. Commun. 13 , 1189 (2022). • T. A. Dessie, W.-H. Huang, D. B. Adam, Y. A. Awoke, C.-H. Wang, J.-L. Chen, C.-W. Pao, N. G. Habtu*, M.-C. Tsai*( 蔡孟哲 ), W.-N. Su*( 蘇威年 ), and B. J. Hwang*( 黃炳照 ), “ Efficient H 2 Evolution Coupled with Anodic Oxidation of Iodide Over Defective Carbon-supported Single-atom Mo-N 4 Electrocatalyst ”, Nano Lett. 22 , 7311 (2022). • S.-W. Hsiao, P.-J. Wu*( 吳品鈞 ), and W.-C. Chou, “ Thermal Effect on the Electronic Properties of ZnO/CdS/CIGSeS Solar Cell at/near the Heterojunction Interfaces ”, ACS Appl. Energy Mater. 5 , 10994 (2022). • A. Joi, A. Lesniewska, D. Dictus, K. C. Tso, K. Venkatraman, Y. Dordi, K. Croes, Z. Tokei, S. K. Yadav, and P. W. Wu*( 吳樸偉 ), “ Doped Ru to Enable Next Generation Barrier-less Interconnect ”, J. Appl. Phys. 132 , 175704 (2022). • Y.-C. Kao, H.-K. Peng, Y.-K. Wang, K.-A. Wu, C.-Y. Wang, Y.-D. Lin, T.-C. Lai, Y.-H. Wu, C.-Y. Lin, S.-W. Hsiao, M.-H. Lee, and P.-J. Wu*( 吳品鈞 ), “ Toward Highly Pure Ferroelectric Hf 1-x Zr x O 2 Thin Films by Tailoring the Strain in an Unstable Thermodynamic System ”, ACS Appl. Electron. Mater. 4 , 3897 (2022). • W. Li, L. Li, Q. Xia, S. Hong, L. Wang, Z. Yao, T.-S. Wu, Y.-L. Soo, H. Zhang, T. W. B. Lo, A. W. Robertson, Q. Liu*( 劉清雅 ), L. Hao*( 郝磊端 ), and Z. Sun* ( 孫振宇 ), “ Lowering C-C Coupling Barriers for Efficient Electrochemical CO 2 Reduction to C 2 H 4 by Jointly Engineering Single Bi Atoms and Oxygen Vacancies on CuO ”, Appl. Catal. B-Environ. 318 , 121823 (2022). ◎ W.-H. Lin, S.-F. Liu, S. Gull, T.-C. Su, K.-J. Tsai, C.-H. Kuo, C.-C. Lin, C.-C. Wang, M.-H. Lin*( 林明憲 ), C.-L. Sun*( 孫嘉良 ), and H.-Y. Chen*( 陳翰儀 ), “ Nanoporous core-shell-structured Multi-wall Carbon Nanotube/Graphene Oxide Nanoribbons as Cathodes and Protection Layer for Aqueous Zinc-ion Capacitors: Mechanism Study of Zinc Dendrite Suppression by In-situ Transmission X-ray Microscopy ”, J. Power Sources 541 , 231627 (2022). • A. Maignan*, M. Schmidt, Y. Prots, O. I. Lebedev, R. Daou, C.-F. Chang, C.-Y. Kuo, Z. Hu, C.-T. Chen, S.-C. Weng, S. G. Altendorf, L.-H. Tjeng, and Y. Grin, “ FeWO 4 Single Crystals: Structure, Oxidation States, and Magnetic and Transport Properties ”, Chem. Mater. 34 , 789 (2022). • A. K. Mensah, B. Marschner, J. Wang, J. Bundschuh, S.-L. Wang, P.-T. Yang, S. M. Shaheen, and J. Rinklebe*, “ Reducing Conditions Increased the Mobilisation and Hazardous Effects of Arsenic in a Highly Contaminated Gold Mine Spoil ”, J. Hazard. Mater. 436 , 129238 (2022). • D.-C. Nguyen, C.-C. Chu, A. K. Anbalagan, C.-H. Lee*( 李志浩 ), and C.-S. Chang*( 張嘉升 ), “ Rietveld Refinement and X-ray Absorption Study on the Bonding States of Lanthanum-based Perovskite-type Oxides La 1-x Ce x CoO 3 ”, Crystals 12 , 50 (2022). • H.-K. Peng, C.-Y. Chiu, Y.-C. Kao, P.-J. Wu, and Y.-H. Wu*( 巫勇賢 ), “ Enhanced Reliability, Switching Speed and Uniformity for Ferroelectric HfZrO x on Epitaxial Ge Film by Post Deposition Annealing for Oxygen Vacancy Control ”, IEEE T. Electron Dev. 69 , 4002 (2022). • H.-K. Peng, C.-M. Liu, Y.-C. Kao, P.-J. Wu, and Y.-H. Wu*( 巫勇賢 ), “ Improved Immunity to Sub-cycling Induced Instability for Triple-level Cell Ferroelectric FET Memory by Depositing HfZrO x on NH 3 Plasma-treated Si ”, IEEE Electron Device Lett. 43 , 1219 (2022). • H.-K. Peng, T.-C. Lai, Y.-C. Kao, C.-M. Liu, P.-J. Wu, and Y.-H. Wu*( 巫勇賢 ), “ Improved Reliability for Back-end-of-line Compatible Ferroelectric Capacitor With 3 Bits/Cell Storage Capability by Interface Engineering and Post Deposition Annealing ”, IEEE Electron Device Lett. 43 , 2180 (2022). • G. Sun, M. M.-J. Li b, K. Nakagawa, G. Li, T.-S. Wu, and Y.-K. Peng*( 彭詠康 ), “ Bulk-to-nano Regulation of Layered Metal Oxide Gears H 2 O 2 Activation Pathway for Its Stoichiometric Utilization in Selective Oxidation Reaction ”, Appl. Catal. B-Environ. 313 , 121461 (2022). • J. Sun, J. Zhou, L. Li, Z. Hu, T.-S. Chan, T. Vitova, S. Song, R. Liu, C. Jing, H. Yu, M. Zhang, J. Rothe*, J.-Q. Wang*( 王建強 ), and L. Zhang*( 張林娟 ), “ Atomic Controllable Anchoring of Uranium into Zirconate Pyrochlore with Ultrahigh Loading Capacity ”, Chem. Commun. 58 , 3469 (2022). • T.-S. Wu, S.-F. Chen, S.-C. Weng, and Y.-L. Soo*( 蘇雲良 ), “ Formation of Co-O Bonds and Reversal of Thermal Annealing Efects Induced by X-ray Irradiation in (Y, Co)-codoped CeO 2 Nanocrystals ”, Sci. Rep. 12 , 1578 (2022). • Q. Xue, B. K. Y. Ng, H. W. Man, T.-S. Wu, Y.-L. Soo, M. M. Li, S. Kawaguchi, K. Y. Wong, S. C. E. Tsang, B. Huang*( 黃勃龍 ), and T. W. B. Lo*( 勞子桓 ), “ Controlled Synthesis of Bi- and Tri-nuclear Cu-oxo Nanoclusters on Metal-organic Frameworks and the Structure-reactivity Correlations ”, Chem. Sci. 13 , 50 (2022). • X. Yang, S. M. Shaheen, J. Wang, D. Hou, Y. S. Ok, S.-L. Wang, H. Wang* ( 王海龍 ), and J. Rinklebe*, “ Elucidating the Redox-driven Dynamic Interactions Between Arsenic and Iron-impregnated Biochar in a Paddy Soil Using Geochemical and Spectroscopic Techniques ”, J. Hazard. Mater. 422 , 126808 (2022). • X. Yang, M. Hinzmann, H. Pan, J. Wang, N. Bolan, D. C. W. Tsang, Y. S. Ok, S.-L. Wang, S. M. Shaheen, H. Wang*( 王海龍 ), and J. Rinklebe*, “ Pig Carcass-derived Biochar Caused Contradictory Effects on Arsenic Mobilization in a Contaminated Paddy Soil Under Fluctuating Controlled Redox Conditions ”, J. Hazard. Mater. 421 , 126647 (2022). • J. Zhang, T.-S. Wu, H. V. Thang, K.-Y. Tseng, X. Hao*( 郝曉東 ), B. Xu, H.-Y. T. Chen*( 陳馨怡 ), and Y.-K. Peng*( 彭詠康 ), “ Cluster Nanozymes with Optimized Reactivity and Utilization of Active Sites for Effective Peroxidase (and Oxidase) Mimicking ”, Small 18 , 2104844 (2022). TLS 08A1 BM − (L-SGM) XPS, UPS ◎ J.-W. Chen, S.-H. Hsieh, S.-S. Wong, Y.-C. Chiu, H.-W. Shiu, C.-H. Wang, Y.-W. Yang, Y.-J. Hsu, D. Convertino, C. Coletti, S. Heun, C.-H. Chen*( 陳家浩 ), and C.-L. Wu*( 吳忠霖 ), “ Hydrogen Spillover and Storage on Graphene with Single- site Ti Catalysts ”, ACS Energ. Lett. 7 , 2297 (2022). • Y.-T. Cheng, H.-W. Wan, J. Kwo*( 郭瑞年 ), M. Hong*( 洪銘輝 ), and T.-W. Pi*( 皮敦文 ), “ A Synchrotron Radiation Photoemission Study of SiGe(001)-2X1 Grown on Ge and Si Substrates: The Surface Electronic Structure for Various Ge Concentrations ”, Nanomaterials 12 , 1309 (2022). • J.-I. Lo, Y.-C. Peng, H.-C. Lu*( 盧曉琪 ), T.-R. Tseng, and B.-M. Cheng*( 鄭炳銘 ), “ Monitoring the Temperature of a Mo/Si Mirror with Photoluminescence in Extreme-ultraviolet Lithography ”, ACS Appl. Electron. Mater. 4 , 3435 (2022). TLS 08B1 BM − AGM • A. Jiménez-Escobar*, A. Ciaravella, C. Cecchi-Pestellini, G. M. Muñoz Caro, C.-H. Huang, N.-E. Sie, and Y.-J. Chen*( 陳俞融 ), “ X-ray-induced Diffusion and Mixing in Layered Astrophysical Ices ”, Astrophys. J. 926 , 176 (2022). • C.P. Wang, B. J. Lin, P.J. Wu, J.R. Shih, Y.D. Chih, J. Chang, C. J. Lin, and Y.C. King*( 金雅琴 ), “ Embedded Micro-detectors for EUV Exposure Control in FinFET CMOS Technology ”, Nanoscale Res. Lett. 17 , 5 (2022). TLS 09A1 U50 − SPEM • T. Amrillah*, M. N. Duong, Y.-X. Chen, Y. Bitla, M. A. Baqiya, F. N. I. Sari, L. T. Quynh, A. Hermawan, F. M. Simanjuntak, C.-H. Chen, K.-H. Wu, and J.-Y. Juang*( 莊振益 ), “ Effects of Surface Polarity on the Structure and Magnetic Properties of Epitaxial hYMnO 3 Thin Films Grown on MgO Substrates ”, ACS Appl. Electron. Mater. 4 , 1603 (2022). • W.-H. Chang, C.-I. Lu, T. H. Yang, S.-T. Yang, K. B. Simbulan, C.-P. Lin, S.-H. Hsieh, J.-H. Chen, K.-S. Li, C.-H. Chen, T.-H. Hou, T.-H. Lu, and Y.-W. Lan* ( 藍彥文 ), “ Defect-engineered Room Temperature Negative Differential Resistance in Monolayer MoS 2 Transistors ”, Nanoscale Horiz. 7 , 1533 (2022). • W.-H. Chen, C.-H. Ma, S.-H. Hsieh, Y.-H. Lai, Y.-C. Kuo, C.-H. Chen, S.-P. Chang, S.-J. Chang, R.-H. Horng*( 洪瑞華 ), and Y.-H. Chu*( 朱英豪 ), “ High Stability Flexible Deep-UV Detector Based on All-oxide Heteroepitaxial Junction ”, ACS Appl. Electron. Mater. 4 , 3099 (2022). • S. M. Gowdru, C.-H. Lin, C.-C. Chang*( 張鈞智 ), Y.-C. Chen, Y.-L. Kuo, C.-C. Chang, S. B. Patil, C.-W. Pao, J.-L. Chen, C.-R. Lee, C.-K. Chang, Y.-C. Chuang, H.-S. Sheu, C.-I. Yang*( 楊振宜 ), and D.-Y. Wang*( 王迪彥 ), “ Revealing the Structural Transformation between the Activity and Stability of 2D and 3D Co-Mo Metal-organic Frameworks for a Highly Active Oxygen Evolution Reaction ”, ACS Sustain. Chem. Eng. 10 , 12297 (2022). • T.-J. Hong, Y.-X. Chen, N. N. Quyen, Y.-H. Chen, C.-H. Chen, B.-H. Huang, J.-Y. Chen, M.-S. Ho, J.-Y. Juang, C.-H. Chen*( 陳家浩 ), and C.-W. Luo*( 羅志偉 ), “ Snapshots of Ambient Aging in 2D-layered GaSe ”, ACS Appl. Electron. Mater. 4 , 3049 (2022). ◎ Y.-C. Lin, Y.-P. Chang, K.-W. Chen, T.-T. Lee, B.-J. Hsiao, T.-H. Tsai, Y.-C. Yang, K.-I. Lin, K. Suenaga, C.-H. Chen, and P.-W. Chiu*( 邱博文 ), “ Patterning and Doping of Transition Metals in Tungsten Dichalcogenides ”, Nanoscale 14 , 16968 (2022). • Y.-Y. Lu*( 盧怡穎 ), Y.-T. Huang, J.-N. Chen, J. Jhou, L.-W. Lan, C.-C. Kuo, J.-H. Hsu, S.-H. Hsieh, C.-H. Chen, and R. Sankar, “ Energy Barrier at Indium/Indium Selenide Nanosheet Interfaces: Implications of Metal-to-insulator Transition for Field-effect Transistor Modeling ”, ACS Appl. Nano Mater. 5 , 1911 (2022). • Y.-Y. Lu*( 盧怡穎 ), Y.-L. Yang, P.-Y. Chuang, J. Jhou, J.-H. Hsu, S.-H. Hsieh, and C.-H. Chen, “ Operando Photoelectron Spectroscopy Analysis of Graphene Field- effect Transistors ”, Nanotechnology 33 , 475702 (2022).