NSRRC Activity Report 2022

Appendix 139 Inelastic X-ray Scattering as a Probe of J eff = 1/2 State in 3d Transition-metal Oxide ”, npj Quantum Mater. 7 , 33 (2022). • A. Singh, H. Y. Huang, C. Lane, J. H. Li, J. Okamoto, S. Komiya, R. S. Markiewicz, A. Bansil, T. K. Lee, A. Fujimori, C. T. Chen, and D. J. Huang*( 黃迪靖 ), “ Acoustic Plasmons and Conducting Carriers in Hole-doped Cuprate Superconductors ”, Phys. Rev. B 105 , 235105 (2022). TPS 44A Quick-scanning X-ray Absorption Spectroscopy • T. A. Abay, W. H. Wanna, T. Natarajan, Y.-F. Tsai, D. Janmanchi, J.-C. Jiang* ( 江志強 ), R. Abu-Reziq*, and S. S.-F. Yu*( 俞聖法 ), “ Selective Oxidation of Benzene by an Iron Oxide Carbonaceous Nanocatalyst Prepared from Iron Perchlorate Salts and Hydrogen Peroxide in Benzene and Acetonitrile ”, Mol. Catal. 526 , 112397 (2022). • D. B. Adam, M.-C. Tsai*( 蔡孟哲 ), Y. A. Awoke, W.-H. Huang, C.-H. Lin, T. Alamirew, A. A. Ayele, Y.-W. Yang, C.-W. Pao, W.-N. Su*( 蘇威年 ), and B. J. Hwang*( 黃炳照 ), “ Engineering Self-supported Ruthenium-titanium Alloy Oxide on 3D Web-like Titania as Iodide Oxidation Reaction Electrocatalyst to Boost Hydrogen Production ”, Appl. Catal. B-Environ. 316 , 121608 (2022). • Y. A. Awoke, M.-C. Tsai*( 蔡孟哲 ), D. B. Adam, A. A. Ayele, S.-C. Yang, W.-H. Huang, J.-L. Chen, C.-W. Pao, C. Y. Mou*( 牟中原 ), W.-N. Su*( 蘇威年 ), and B. J. Hwang*( 黃炳照 ), “ The Synergistic effect Pt 1 -W Dual Sites as a Highly Active and Durable Catalyst for Electrochemical Methanol Oxidation ”, Electrochim. Acta 432 , 141161 (2022). • A. A. Ayele, M.-C. Tsai*( 蔡孟哲 ), D. B. Adam, Y. A. Awoke, W.-H. Huang, C.-Y. Chang, S.-C. Liao, P.-Y. Huang, J.-L. Chen, C.-W. Pao, W.-N. Su*( 蘇威年 ), and B. J. Hwang*( 黃炳照 ), “ Electrochemical Oxidation of Ethylene Glycol on TiO 2 -supported Platinum Single-atom Catalyst into Valuable Chemicals in Alkaline Media ”, Appl. Catal. A-Gen. 646 , 118861 (2022). • L. Bu*( 蔔令正 ), F. Ning, J. Zhou, C. Zhan, M. Sun, L. Li, Y. Zhu, Z. Hu, Q. Shao, X. Zhou, B. Huang*( 黃勃龍 ), and X. Huang*( 黃小青 ), “ Three-dimensional Porous Platinum-tellurium-rhodium Surface/Interface Achieve Remarkable Practical Fuel Cell Catalysis ”, Energ. Environ. Sci. 15 , 3877 (2022). • C.-H. Chen, Z.-H. Su, Y.-H. Lou, Y.-J. Yu, K.-L. Wang, G.-L. Liu, Y.-R. Shi, J. Chen, J.-J. Cao, L. Zhang, X.-Y. Gao, and Z.-K. Wang*( 王照奎 ), “ Full-dimensional Grain Boundary Stress Release for Flexible Perovskite Indoor Photovoltaics ”, Adv. Mater. 34 , 2200320 (2022). • C.-S. Chen*( 陳敬勳 ), T.-C. Chen, K.-L. Chiu, H.-C. Wu, C.-W. Pao, C.-L. Chen, H.-C. Hsu, and H.-M. Kao*( 高憲明 ), “ Silver Particles Deposited onto Magnetic Carbon Nanofibers as Highly Active Catalysts for 4-nitrophenol Reduction ”, Appl. Catal. B-Environ. 315 , 121596 (2022). ◎ K.-Y. Chen, Y.-M. Tzou, L.-C. Hsu, J.-W. Guo, Y.-L. Cho, H.-Y. Teah, Y.-C. Hsieh, and Y.-T. Liu*( 劉雨庭 ), “ Oxidative Removal of Thallium(I) Using Al Beverage Can Waste with Amendments of Fe: Tl Speciation and Removal Mechanisms ”, Chem. Eng. J. 427 , 130846 (2022). • L. Chen, P. Verma, K. Hou, Z. Qi, S. Zhang, Y.-S. Liu, J. Guo, V. Stavila, M. D. Allendorf, L. Zheng, M. Salmeron, D. Prendergast*, G. A. Somorjai*, and J. Su*, “ Reversible Dehydrogenation and Rehydrogenation of Cyclohexane and Methylcyclohexane by Singlesite Platinum Catalyst ”, Nat. Commun. 13 , 1092 (2022). • W. Chen, Y. Wang, B. Wu, J. Shi, Y. Li, L. Xu, C. Xie, W. Zhou, Y.-C. Huang, T. Wang, S. Du, M. Song, D. Wang, C. Chen, J. Zheng, J. Liu, C.-L. Dong, Y. Zou, J. Chen, and S. Wang*( 王雙印 ), “ Activated Ni-OH Bond in Catalyst Facilitates Nucleophile Oxidation Reaction ”, Adv. Mater. 34 , 2105320 (2022). • C.-C. Cheng, Y.-X. Yeh, Y.-C. Ting, S.-H. Lin, K. Sasaki, Y. M. Choi*( 崔容滿 ), and S.-Y. Lu*( 呂世源 ), “ Modulation of the Coordination Environment Enhances the Electrocatalytic Efficiency of Mo Single Atoms toward Water Splitting ”, J. Mater. Chem. A 10 , 8784 (2022). • F. Cheng, X. Peng, L. Hu, B. Yang, Z. Li, C.-L. Dong, J.-L. Chen, L.-C. Hsu, L. Lei, Q. Zheng, M. Qiu*( 邱明 ), L. Dai*( 戴黎明 ), and Y. Hou*( 侯陽 ), “ Accelerated Water Activation and Stabilized Metal-organic Framework via Constructing Triangular Active-regions for Ampere-level Current Density Hydrogen Production ”, Nat. Commun. 13 , 6486 (2022). • C.-T. Chiu, Y.-J. Teng, B.-H. Dai, I.-Y. Tsao, W.-C. Lin, K.-W. Wang, L.-C. Hsu, Y.-C. Chang, C.-T. Li, H. T. T. Nguyen, C.-Y. Chiang*( 蔣慶有 ), and W.-H. Hung* ( 洪緯璿 ), “ Novel High-entropy Ceramic/Carbon Composite Materials for the Decomposition of Organic Pollutants ”, Mater. Chem. Phys. 275 , 125274 (2022). • W. C. Chung, S. Y. Hsu, C. W. Pao, Y. C. Chuang, K. T. Lu, and J. M. Chen* ( 陳錦明 ), “ Correlation of Photocatalytic CO 2 Conversion and Electronic Structure of UiO-66 and Cu-UiO-66-NH 2 under Irradiation Studied by In-situ X-ray Absorption Spectroscopy ”, J. CO2 Util. 60 , 101961 (2022). • T. A. Dessie, W.-H. Huang, D. B. Adam, Y. A. Awoke, C.-H. Wang, J.-L. Chen, C.-W. Pao, N. G. Habtu*, M.-C. Tsai*( 蔡孟哲 ), W.-N. Su*( 蘇威年 ), and B. J. Hwang*( 黃炳照 ), “ Efficient H 2 Evolution Coupled with Anodic Oxidation of Iodide Over Defective Carbon-supported Single-atom Mo-N 4 Electrocatalyst ”, Nano Lett. 22 , 7311 (2022). • J. Dong, Y. Cheng, Y. Li, X. Peng, R. Zhang, H.-T. Wang, C. Wang, X. Li, P. Ou, C.-W. Pao, L. Han*( 韓麗麗 ), W.-F. Pong, Z. Lin, J. Luo, and H. L. Xin*( 忻獲麟 ), “ Abundant (110) Facets on PdCu 3 Alloy Promote Electrochemical Conversion of CO 2 to CO ”, ACS Appl. Mater. Interfaces 14 , 41969 (2022). • M. B. Getahun, E. B. Santiko, T. Imae*, C.-L. Chiang, and Y.-G. Lin*( 林彥谷 ), “ Photocatalytic Conversion of Gaseous Carbon Dioxide to Methanol on CuO/ZnO- embedded Carbohydrate Polymer Films ”, Appl. Surf. Sci. 604 , 154515 (2022). • S. M. Gowdru, C.-H. Lin, C.-C. Chang*( 張鈞智 ), Y.-C. Chen, Y.-L. Kuo, C.-C. Chang, S. B. Patil, C.-W. Pao, J.-L. Chen, C.-R. Lee, C.-K. Chang, Y.-C. Chuang, H.-S. Sheu, C.-I. Yang*( 楊振宜 ), and D.-Y. Wang*( 王迪彥 ), “ Revealing the Structural Transformation between the Activity and Stability of 2D and 3D Co-Mo Metal-organic Frameworks for a Highly Active Oxygen Evolution Reaction ”, ACS Sustain. Chem. Eng. 10 , 12297 (2022). • D. Guan*( 管大秦 ), J. Zhong, H. Xu, Y.-C. Huang, Z. Hu, B. Chen, Y. Zhang, M. Ni, X. Xu, W. Zhou, and Z. Shao*( 邵宗平 ), “ A Universal Chemical-induced Tensile Strain Tuning Strategy to Boost Oxygen-evolving Electrocatalysis on Perovskite Oxides ”, Appl. Phys. Rev. 9 , 011422 (2022). • L. Han, H. Cheng, W. Liu, H. Li, P. Ou, R. Lin, H.-T. Wang, C.-W. Pao, A. R. Head, C.-H. Wang, X. Tong, C.-J. Sun, W.-F. Pong, J. Luo*( 羅俊 ), J.-C. Zheng* ( 鄭金成 ), and H. L. Xin*( 忻獲麟 ), “ A Single-atom Library for Guided Monometallic and Concentration-complex Multimetallic Designs ”, Nat. Mater. 21 , 681 (2022). • L. Han, P. Ou, W. Liu, X. Wang, H.-T. Wang, R. Zhang, C.-W. Pao, X. Liu* ( 劉熙俊 ), W.-F. Pong, J. Song, Z. Zhuang, M. V. Mirkin, J. Luo, and H. L. Xin* ( 忻獲麟 ), “ Design of Ru-Ni Diatomic Sites for Efficient Alkaline Hydrogen Oxidation ”, Sci. Adv. 8 , eabm3779 (2022). • L. Han*( 韓麗麗 ), X. Peng, H.-T. Wang, P. Ou, Y. Mi, C.-W. Pao, J. Zhou, J. Wang, X. Liu, W.-F. Pong, J. Song, Z. Lin, J. Luo, and H. L. Xin*( 忻獲麟 ), “ Chemically Coupling SnO 2 Quantum Dots and MXene for Efficient CO 2 Electroreduction to Formate and Zn-CO 2 Battery ”, P. Natl. Acad. Sci. USA 119 , e2207326119 (2022). ◎ T.-Y. Han, C.-H. Lin, Y.-S. Lin, C.-M. Yeh, Y.-A. Chen, H.-Y. Li, Y.-T. Xiao, J.-W. Chang, A.-C. Su, U.-S. Jeng*( 鄭有舜 ), and H.-H. Chou*( 周鶴修 ), “ Autonomously Self-healing and Ultrafast Highly-stretching Recoverable Polymer through Trans-octahedral Metal-ligand Coordination for Skin-inspired Tactile Sensing ”, Chem. Eng. J. 438 , 135592 (2022). • F. H. Hsu, S. Y. Hsu, B. H. Chen, J. L. Chen, J. M. Chen*( 陳錦明 ), and K. T. Lu* ( 盧桂子 ), “ Correlation of the Crystal Structure and Ion Storage Behavior of MoO 3 Electrode Materials for Aluminum-ion Energy Storage Studied Using in Situ X-ray Spectroscopy ”, Nanoscale 14 , 7502 (2022). • L.-C. Hsu, Y.-M. Tzou, W.-H. Liao, H. Y. Teah, and Y.-T. Liu*( 劉雨庭 ), “ Transformation of Sedimentary and Colloidal Phosphorus Across the Land-sea Margin Received Effluents from Agricultural and Municipal Activities ”, J. Clean. Prod. 379 , 134686 (2022). • J. Hua, Y.-H. Fei, C. Feng, C. Liu*( 劉承帥 ), S. Liang, S.-L. Wang, and F. Wu, “ Anoxic Oxidation of As(III) During Fe(II)-induced Goethite Recrystallization: Evidence and Importance of Fe(IV) Intermediate ”, J. Hazard. Mater. 421 , 126806 (2022). • H. Huang, D. Yu, F. Hu, S.-C. Huang, J. Song, H.-Y. Chen, L. Li, and S. Peng* ( 彭生杰 ), “ Clusters Induced Electron Redistribution to Tune Oxygen Reduction Activity of Transition Metal Single-atom for Metal-air Batteries ”, Angew. Chem. Int. Edit. 61 , e202116068 (2022). • Y.-C. Huang, W. Chen, Z. Xiao, Z. Hu, Y.-R. Lu, J.-L. Chen, C.-L. Chen, H.-J. Lin, C.- T. Chen, K. T. Arul, S. Wang*( 王雙印 ), C.-L. Dong*( 董崇禮 ), and W.-C. Chou* ( 周武清 ), “ In Situ/Operando Soft X-ray Spectroscopic Identification of a Co 4+ Intermediate in the Oxygen Evolution Reaction of Defective Co 3 O 4 Nanosheets ”, J. Phys. Chem. Lett. 13 , 8386 (2022). • Y.-P. Huang, C.-W. Tung, T.-L. Chen, C.-S. Hsu, M.-Y. Liao*( 廖美儀 ), H.-C. Chen* ( 陳効謙 ), and H. M. Chen*( 陳浩銘 ), “ In Situ Probing the Dynamic Reconstruction of Copper-zinc Electrocatalysts for CO 2 Reduction ”, Nanoscale 14 , 8944 (2022). • S.-F. Hung, A. Xu, X. Wang, F. Li, S.-H. Hsu, Y. Li, J. Wicks, E. G. Cervantes, A. S. Rasouli, Y. C. Li, M. Luo, D.-H. Nam, N. Wang, T. Peng, Y. Yan, G. Lee, and E. H. Sargent*, “ A Metal-supported Single-atom Catalytic Site Enables Carbon Dioxide Hydrogenation ”, Nat. Commun. 13 , 819 (2022). • S.-F. Hung*( 洪崧富 ), F.-Y. Wu, Y.-H. Lu, T.-J. Lee, H.-J. Tsai, P.-H. Chen, Z.-Y. Lin, G.-L. Chen, W.-Y. Huang, and W.-J. Zeng, “ Operando X-ray Absorption Spectroscopic Studies of the Carbon Dioxide Reduction Reaction in a Modified Flow Cell ”, Catal. Sci. Technol. 12 , 2739 (2022). • X. Kuai, K. Li, J. Chen, H. Wang*( 王昊 ), J. Yao, C.-L. Chiang, T. Liu, H. Ye, J. Zhao, Y.-G. Lin, L. Zhang, V. Nicolosi*, and L. Gao*( 高立軍 ), “ Interfacial Engineered Vanadium Oxide Nanoheterostructures Synchronizing HighEnergy