NSRRC Activity Report 2022

138 NSRRC ACTIVITY REPORT 2022 Adv. Funct. Mater. 32 , 2200880 (2022). • S. N. Afraj, M.-H. Lin, C.-Y. Wu, A. Velusamy, P.-Y. Huang, T.-Y. Peng, J.-C. Fu, S.-H. Tung, M.-C. Chen*( 陳銘洲 ), and C.-L. Liu*( 劉振良 ), “ Solution Processable Dithioalkylated Methylidenyl Cyclopentadithiophene Based Quinoidal Small Molecules for n-type Organic Field-effect Transistors ”, J. Mater. Chem. C 10 , 14496 (2022). • C.-I. Chang, E. M. Woo*( 吳逸謨 ), and S. Nagarajan, “ Grating Assembly Dissected in Periodic Bands of Poly(Butylene Adipate) Modulated with Poly (Ethylene Oxide) ”, Polymers 14 , 4781 (2022). • S.-J. Chang, S.-Y. Wang, Y.-C. Huang, J. H. Chih, Y.-T. Lai, Y.-W. Tsai, J.-M. Lin, C.-H. Chien, Y.-T. Tang*( 唐英瓚 ), and C. Hu*( 胡正明 ), “ Van der Waals Epitaxy of 2D h-AlN on TMDs by Atomic Layer Deposition at 250°C ”, Appl. Phys. Lett. 120 , 162102 (2022). ◎ Y. Chen, H.-Y. Chang, M.-T. Lee, Z.-R. Yang, C.-H. Wang, K.-Y. Wu*( 吳冠毅 ), W.-T. Chuang*( 莊偉綜 ), and C.-L. Wang*( 王建隆 ), “ Dual-axis Alignment of Bulk Artificial Water Channels by Directional Water-induced Self-assembly ”, J. Am. Chem. Soc. 144 , 7768 (2022). • T. C. Hsieh, Y.-M. Liao, W.-F. Hsu, H.-L. Kao*( 高慧玲 ), Y,-C, Huang, S,-J, Chang*( 張書睿 ), Y.-S. Chen, and Y.-P. Hsieh, “ Mechanistic Insights into Low- temperature Epitaxial Growth of Aluminum Nitride Films on Layered Transition Metal Dichalcogenides ”, J. Vac. Sci. Technol. A 40 , 062705 (2022). • T. Isono*, R. Komaki, N. Kawakami, K. Chen, H.-L. Chen, C. Lee, K. Suzuki, B. J. Ree, H. Mamiya, T. Yamamoto, R. Borsali, K. Tajima, and T. Satoh*, “ Tailored Solid-state Carbohydrate Nanostructures Based on Star-shaped Discrete Block Co-oligomers ”, Biomacromolecules 23 , 3978 (2022). • B.-H. Jiang, Y.-J. Peng, Y.-W. Su, J.-F. Chang, C.-C. Chueh, T.-S. Shieh, C.-I. Huang*( 黃慶怡 ), and C.-P. Chen*( 陳志平 ), “ A Polymer Donor with Versatility for Fabricating High-performance Ternary Organic Photovoltaics ”, Chem. Eng. J. 431 , 133950 (2022). • K. Jiang, S.-H. Hong, S.-H. Tung, and C.-L. Liu*( 劉振良 ), “ Effects of Cation Size on Thermoelectricity of PEDOT:PSS/Ionic Liquid Hybrid Films for Wearable Thermoelectric Generator Application ”, J. Mater. Chem. A 10 , 18792 (2022). ◎ L.-T. Juan, S.-H. Lin, C.-W. Wong, U.-S. Jeng, C.-F. Huang, and S.-H. Hsu* ( 徐善慧 ), “ Functionalized Cellulose Nanofibers as Crosslinkers to Produce Chitosan Self-healing Hydrogel and Shape Memory Cryogel ”, ACS Appl. Mater. Interfaces 14 , 36353 (2022). • A. Khan, S. Ahmed, B.-Y. Sun, Y.-C. Chen, W.-T. Chuang, Y.-H. Chan, D. Gupta, P.- W. Wu, and H.-C. Lin*( 林宏洲 ), “ Self-healable and Anti-freezing Ion Conducting Hydrogel-based Artificial Bioelectronic Tongue Sensing toward Astringent and Bitter Tastes ”, Biosens. Bioelectron. 198 , 113811 (2022). • C.-H. Kuan, G.-S. Luo, S. Narra, S. Maity, H. Hiramatsu, Y.-W. Tsai, J.-M. Lin, C.-H. Hou, J.-J. Shyue, and E. W.-G. Diau*( 刁維光 ), “ How Can a Hydrophobic Polymer PTAA Serve as a Hole-transport Layer for an Inverted Tin Perovskite Solar Cell? ”, Chem. Eng. J. 450 , 138037 (2022). • C.-H. Kuan, J.-M. Chih, Y.-C. Chen, B.-H. Liu, C.-H. Wang, C.-H. Hou, J.-J. Shyue, and E. W.-G. Diau*( 刁維光 ), “ Additive Engineering with Triple Cations and Bifunctional Sulfamic Acid for Tin Perovskite Solar Cells Attaining a PCE Value of 12.5% without Hysteresis ”, ACS Energ. Lett. 7 , 4436 (2022). • S. Kumar, T. Marcato, F. Krumeich, Y.-T. Li, Y.-C. Chiu, and C.-J. Shih*( 施智仁 ), “ Anisotropic Nanocrystal Superlattices Overcoming Intrinsic Light Outcoupling Efficiency Limit in Perovskite Quantum Dot Light-emitting Diodes ”, Nat. Commun. 13 , 2106 (2022). • Y.-T. Lan, Q.-P. Cheng, J. Xu, S.-H. Lin, J.-M. Lin, and S.-H. Hsu*( 徐善慧 ), “ Gelation and the Self-healing Behavior of the Chitosan-catechol Hydrogel ”, Polymers 14 , 4614 (2022). • C.-C. Lin, A. Velusamy, S.-H. Tung, I. Osaka, M.-C. Chen*( 陳銘洲 ), and C.-L. Liu*( 劉振良 ), “ Tunable Photoelectric Properties of n-type Semiconducting Polymer: Small Molecule Blends for Red Light Sensing Phototransistors ”, Adv. Opt. Mater. 10 , 2102650 (2022). • I.-M. Lin, C.-C. Hsu, T.-C. Yu, S.-W. Kuo, W.-T. Chuang, and Y.-W. Chiang* ( 蔣酉旺 ), “ Propagatable Hierarchical Architectures from Dispersive Fragments to Periodic Nanosheets within Phase-separated Nanostructures by Controlling Guest- host Interaction ”, Macromolecules 55 , 9048 (2022). • Y. Liu, S.-H. Lin, W.-T. Chuang, N.-T. Dai, and S.-H. Hsu*( 徐善慧 ), “ Biomimetic Strain-stiffening in Chitosan Self-healing Hydrogels ”, ACS Appl. Mater. Interfaces 14 , 16032 (2022). • J.-H. Lu*( 盧榮宏 ), B.-H. Jiang, F.-C. Hsiao, Y.-C. Peng, Y.-W. Su, Y.-R. Lin, T.-H. Tsai, M.-N. Shiu, C.-Y. Lin, and Y.-T. Fang, and C.-P. Chen*( 陳志平 ), “ High- performance Organic Photodiodes for Blue-light Hazard Detection ”, Chem. Eng. J. 437 , 135327 (2022). ◎ X.-F. Luo, J. Patra, W.-T. Chuang, T. X. Nguyen, J.-M. Ting, J. Li, C.-W. Pao* ( 包志文 ), and J.-K. Chang*( 張仍奎 ), “ Charge-discharge Mechanism of High-entropy Co-free Spinel Oxide Toward Li + Storage Examined Using Operando Quick-scanning X-ray Absorption Spectroscopy ”, Adv. Sci. 9 , 2201219 (2022). • A. Z. Melaku, W.-T. Chuang, C.-W. Chiu, J.-Y. Lai, and C.-C. Cheng*( 鄭智嘉 ), “ Controlling the Hierarchical Structures of Molybdenum Disulfide Nanomaterials via Self-assembly of Supramolecular Polymers in Water ”, Chem. Mater. 34 , 3333 (2022). • S. Nagarajan, H.-H. Li, E. M. Woo*( 吳逸謨 ), W.-T. Chuang, and Y. W. Tsai, “ Single Crystals Self-assembled to Sector-face Dendritic Aggregates by Synchrotron Microbeam X-ray Analysis on Poly(Ethylene Succinate) ”, Macromol. Chem. Phys. 223 , 2200114 (2022). • B. Nouri, C.-Y. Chen, J.-M. Lin, and H.-L. Chen*( 陳信龍 ), “ Phase Control of Colloid-like Block Copolymer Micelles by Tuning Size Distribution via Thermal Processing ”, Macromolecules 55 , 9820 (2022). • C. M. Septani, C.-C. Wang, and Y.-S. Sun*( 孫亞賢 ), “ Oxygen Reduction Reaction of Block Copolymer Template-directed Porous Carbon Catalysts ”, ACS Appl. Energy Mater. 5 , 897 (2022). • C. M. Septani, M.-F. Ku, C.-Y. Chen, J.-M. Lin, and Y.-S. Sun*( 孫亞賢 ), “ Micellization, Aggregation, and Gelation of Polystyrene-block-poly(Ethylene Oxide) in Cosolvents Added with Hydrochloric Acid ”, Colloid. Surface. A 652 , 129857 (2022). • Z.-H. Shi, F.-M. Hsu, B. W. Mansel, H.-L. Chen, L. Fruk, W.-T. Chuang*( 莊偉綜 ), and Y.-C. Hung*( 洪毓玨 ), “ Kinetics and Mechanism of In Situ Metallization of Bulk DNA Films ”, Nanoscale Res. Lett. 17 , 18 (2022). • P. Y. Siboro, V. K. T. Nguyen, Y.-B. Miao, A. K. Sharma, F.-L. Mi, H.-L. Chen, K.-H. Chen, Y.-T. Yu, Y. Chang*( 張燕 ), and H.-W. Sung*( 宋信文 ), “ Ultrasound- activated, Tumor-specific In Situ Synthesis of a Chemotherapeutic Agent Using ZIF-8 Nanoreactors for Precision Cancer Therapy ”, ACS Nano 16 , 12403 (2022). • H.-W. Su, I.-M. Lin, Y.-J. Yeh, and Y.-W. Chiang*( 蔣酉旺 ), “ Detection of Extremely Low- and High-concentration Organic Acids by a Highly-aligned Lamellar Block Copolymer Photonic Crystal Film ”, Mater. Chem. Phys. 287 , 126256 (2022). • A. Velusamy, Y.-C. Yang, C.-C. Lin, S. N. Afraj, K. Jiang, P.-S. Chen, S.-L. Yau, I. Osaka, S.-H. Tung, M.-C. Chen*( 陳銘洲 ), and C.-L. Liu*( 劉振良 ), “ Solution Processable Pentafluorophenyl End-capped Dithienothiophene Organic Semiconductors for Hole-transporting Organic Field Effect Transistors ”, Adv. Electron. Mater. 8 , 2100648 (2022). • C.-C. Wong, C.-X. Lu, E.-C. Cho, P.-W. Lee, N.-W. Chi, P.-Y. Lin, P.-R. Jheng, H.-L. Chen, B. W. Mansel, Y.-M. Chen, C.-H. Chen, and E.-Y. Chuang*( 莊爾元 ), “ Calcium Peroxide Aids Tyramine-alginate gel to Crosslink with Tyrosinase for Efficient Cartilage Repair ”, Int. J. Biol. Macromol. 208 , 299 (2022). • C.-H. Wu, Y.-C. Huang, Y.-T. Ho, S.-J. Chang*( 張書睿 ), S.-K. Wu, C.-H. Huang, W.-C. Chou, and C.-S. Yang*( 楊祝壽 ), “ Solid Phase Epitaxy of Single Phase Two- dimensional Layered InSe Grown by MBE ”, Nanomaterials 12 , 2435 (2022). • C.-Y. Wu, A. Z. Melaku, W.-T. Chuang, and C.-C. Cheng*( 鄭智嘉 ), “ Manipulating the Self-assembly Behavior of Graphene Nanosheets via Adenine- functionalized Biodegradable Polymers ”, Appl. Surf. Sci. 572 , 151437 (2022). • W.-N. Wu, T.-H. Tu, C.-H. Pai, K.-H. Cheng, S.-H. Tung, Y.-T. Chan*( 詹益慈 ), and C.-L. Liu*( 劉振良 ), “ Metallo-supramolecular Rod-coil Block Copolymer Thin Films for Stretchable Organic Field Effect Transistor Application ”, Macromolecules 55 , 10670 (2022). • J. Xu, C.-H. Tai, T.-Y. Chen, and S.-H. Hsu*( 徐善慧 ), “ An Anti-inflammatory Electroconductive Hydrogel with Self-healing Property for the Treatment of Parkinson’s Disease ”, Chem. Eng. J. 446 , 137180 (2022). • Y.-Y. Yu*( 游洋雁 ), C.-I. Liu, Y.-C. Peng, B.-H. Jiang, Y.-W. Su, S.-J. Liu, and C.-P. Chen*( 陳志平 ), “ Ambient-stable Near-infrared Organic Photodetectors with Ultrahigh Detectivity and Ultrafast Response for Biometric Monitoring ”, Adv. Electron. Mater. 8 , 2200585 (2022). TPS 31A Projection X-ray Microscopy ◎ T. Y. Chen, L.-W. Kuo*( 郭力維 ), D. Brown, J. Si, T.-J. Meng, H.-S. Sheu, Y.-F. Song, and G.-C. Yin, “ Lightning-induced Features on Granitic Gneiss and Its Implication for Rare Lightning Scars from the Geological Record ”, Contrib. Mineral. Petrol. 177 , 111 (2022). • M.-Y. Hsu*( 徐名瑩 ), C.-Y. Lee, H.-S. Fung, B.-Y. Chen, and G.-C. Yin, “ Water- cooled Magnetic Coupling Drive Attenuator Design for Wiggler Light Source in the TPS 31A Beamline ”, J. Synchrotron Radiat. 29 , 888 (2022). TPS 41A Soft X-ray Scattering • Y.-S. Chen, Z. Bao, W.-T. Huang, A. Lazarowska, N. Majewska, S. Mahlik, G. Leniec, S. M. Kaczmarek, H.-Y. Huang, C.-I. Wu, D.-J. Huang, and R.-S. Liu* ( 劉如熹 ), “ Effect of Temperature and Pressure on Structural and Optical Properties of Organic-inorganic Hybrid Manganese Halides ”, Inorg. Chem. 61 , 2595 (2022). • H. Y. Huang, A. Singh, C. I. Wu, J. D. Xie, J. Okamoto, A. A. Belik, E. Kurmaev, A. Fujimori, C. T. Chen, S. V. Streltsov*, and D. J. Huang*( 黃迪靖 ), “ Resonant